Search results for "thermodynamic equilibrium"
showing 10 items of 80 documents
Dual-Mode Chiral Self-Assembly of Cone-Shaped Subphthalocyanine Aromatics
2020
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.0c07291
Chromospheric evaporation and phase mixing of Alfvén waves in coronal loops
2020
Phase mixing of Alfv\'en waves has been studied extensively as a possible coronal heating mechanism but without the full thermodynamic consequences considered self-consistently. It has been argued that in some cases, the thermodynamic feedback of the heating could substantially affect the transverse density gradient and even inhibit the phase mixing process. In this paper, we use MHD simulations with the appropriate thermodynamical terms included to quantify the evaporation following heating by phase mixing of Alfv\'en waves in a coronal loop and the effect of this evaporation on the transverse density profile. The numerical simulations were performed using the Lare2D code. We set up a 2D l…
Effects of organic aerosol constituents on extinction and absorption coefficients and liquid water contents of fogs and clouds
1978
We have speculated on the influence of organic material on extinction and absorption coefficients and liquid water content of fogs and of clouds immediately after their condensational stage. It results therefore, that the reduction of the speed of growth from fog to cloud droplets due to the presence of organic films largely reduces the properties mentioned. Compared to that their increase coming from the surface tension reduction due to organic material being dissolved or building up films is expected to be less effective.
A new approach to analysis of relationships between 137Cs activity concentrations in forest soil horizons
2013
The measurements results of 137Cs activity concentrations in forest soil profiles are discussed. In studies some simplifications were considered. First of them concerns disregarding of soil subtype in data analysis. However initially this parameter was considered in data analysis, it was finally ignored. The second assumption drops information about specific soil horizon. Description of 137Cs accumulation is based on relationships between its relative activity concentrations in soil layers. The model formulation was based on the results of exploratory data analysis of the relative 137Cs activity concentrations. In studies the methods designed for compositional data analysis were used. The r…
Computer Simulations of the Electric Interactions between the Phospholipid Head-Groups and Ionic Admixtures in the Membrane Surface
2001
Some phospholipids (e.g. lecithin) form a system of electric dipoles on the membrane surface layer. In the case of lecithin the positive dipole charge is located on the choline and the negative one on the phosphoric molecule group. These dipoles are arranged almost parallel to the membrane surface. Taking the dipole membrane structure as a base for further investigations, a computer model of the electrostatic interaction between the dipole system and the ionic admixture was investigated. The model presumes hexagonal centered or a rectangular flat geometry of the 121 dipoles distribution. The dipoles may rotate freely around round the motionless symmetry axis perpendicular to the system surf…
Nonstationary flow surface theory for modeling the viscoplastic behaviors of soils
2016
Abstract This paper presents a three-dimensional elastic viscoplastic model that can describe the time-dependent behaviors of soft clays. The constitutive model is formulated based on the nonstationary flow surface theory and incorporates new developments, including (i) an improved definition of the nonstationary flow surface that is capable of capturing the stress–strain behaviors under different loading paths, (ii) a unique stress–strain—viscoplastic-strain-rate equation that is able to explicitly describe the nonstationary flow surface, and (iii) a final stable state concept that identifies the final equilibrium state at the end of creep and stress relaxation, which is also used to simpl…
The Properties of Atmospheric Aerosol Particles as Functions of the Relative Humidity at Thermodynamic Equilibrium with the Surrounding Moist Air
1976
Publisher Summary The chapter addresses the problems in aerosol measuring techniques and selection of sampling and measuring methods. Theoretic evaluation of mass, size, mean density, and mean refractive index as functions of the relative humidity is discussed. The chapter also discusses techniques for measuring the mass as a function of the relative humidity; determination of the mean density; and measuring the mean complex index of refraction. Results of the measurements, discussion of the results, coefficients of mass increase, mean densities and real parts of the mean complex index of refractions, and applicability of the results are also described. Finally, the chapter then reviews the…
Thermalization and condensation in an incoherently pumped passive optical cavity
2011
International audience; We study theoretically and numerically the condensation and the thermalization of classical optical waves in an incoherently pumped passive Kerr cavity. We show that the dynamics of the cavity exhibits a turbulent behavior that can be described by the wave turbulence theory. A mean-field kinetic equation is derived, which reveals that, in its high finesse regime, the cavity behaves essentially as a conservative Hamiltonian system. In particular, the intracavity turbulent field is shown to relax adiabatically toward a thermodynamic equilibrium state of energy equipartition. As a consequence of this effect of wave thermalization, the incoherent optical field undergoes …
Gibbs equation in the nonlinear nonequilibrium thermodynamics of dilute nonviscous gases
2003
AbstractThis paper deals with the derivation of the Gibbs equation for a nonviscous gas in the presence of heat flux. The analysis aims to shed some light on the physical interpretation of thermodynamic potentials far from equilibrium. Two different definitions for the chemical potential and thermodynamic pressure far from equilibrium are introduced: nonequilibrium chemical potential and nonequilibrium thermodynamic pressure at constant heat flux q and nonequilibrium chemical potential and nonequilibrium thermodynamic pressure at constant J = Vq, where V is the specific volume.
Criteria for validity of thermodynamic equations from non-equilibrium molecular dynamics simulations
2008
Abstract The assumption of local equilibrium is validated in four different systems where heat and mass are transported. Mass fluxes up to 13 kmol / m 2 s and temperature gradients up to 10 12 K / m were used. A two-component mixture, two vapor–liquid interfaces, a chemical reaction in a temperature gradient and gas adsorbed in zeolite were studied using non-equilibrium molecular dynamics simulations. In all cases, we verified that thermodynamic variables obeyed normal thermodynamic relations, with an accuracy better than 5%. The heat and mass fluxes, and the reaction rate were linearly related to the driving forces. Onsager's reciprocal relations were validated for two systems. Equipartiti…