Search results for "tit"
showing 10 items of 26608 documents
Injection and ultrafast regeneration in dye-sensitized solar cells
2014
Injection of an electron from the excited dye molecule to the semiconductor is the initial charge separation step in dye-sensitized solar cells (DSC's). Though the dynamics of the forward injection process has been widely studied, the results reported so far are controversial, especially for complete DSC's. In this work, the electron injection in titanium dioxide (TiO2) films sensitized with ruthenium bipyridyl dyes N3 and N719 was studied both in neat solvent and in a typical iodide/triiodide (I-/I3 -) DSC electrolyte. Transient absorption (TA) spectroscopy was used to monitor both the formation of the oxidized dye and the arrival of injected electrons to the conduction band of TiO2. Emiss…
A singularly perturbed Kirchhoff problem revisited
2020
Abstract In this paper, we revisit the singularly perturbation problem (0.1) − ( ϵ 2 a + ϵ b ∫ R 3 | ∇ u | 2 ) Δ u + V ( x ) u = | u | p − 1 u in R 3 , where a , b , ϵ > 0 , 1 p 5 are constants and V is a potential function. First we establish the uniqueness and nondegeneracy of positive solutions to the limiting Kirchhoff problem − ( a + b ∫ R 3 | ∇ u | 2 ) Δ u + u = | u | p − 1 u in R 3 . Then, combining this nondegeneracy result and Lyapunov-Schmidt reduction method, we derive the existence of solutions to (0.1) for ϵ > 0 sufficiently small. Finally, we establish a local uniqueness result for such derived solutions using this nondegeneracy result and a type of local Pohozaev identity.
Calibration of an airborne HO<sub><i>x</i></sub> instrument using the All Pressure Altitude-b…
2020
Abstract. Laser-induced fluorescence (LIF) is a widely used technique for both laboratory-based and ambient atmospheric chemistry measurements. However, LIF instruments require calibrations in order to translate instrument response into concentrations of chemical species. Calibration of LIF instruments measuring OH and HO2 ( HOx ) typically involves the photolysis of water vapor by 184.9 nm light, thereby producing quantitative amounts of OH and HO2 . For ground-based HOx instruments, this method of calibration is done at one pressure (typically ambient pressure) at the instrument inlet. However, airborne HOx instruments can experience varying cell pressures, internal residence times, tempe…
Experimental investigation on different rainfall energy harvesting structures
2018
In this paper proposes an experimental comparison between different rainfall harvesting devices and the study of the corresponding electrical rectifying circuit. More in detail, three harvesting structures are considered: the cantilever, the bridge and the floating circle. For each of the proposed structure, different waveforms have been acquired and discussed. The processed data have been compared in order to suggest the best choice for the rectifying circuit, from the simplest one to the most endorsed in the technical literature.
A General Mathematical Formulation for the Determination of Differential Leakage Factors in Electrical Machines with Symmetrical and Asymmetrical Ful…
2018
This paper presents a simple and general mathematical formulation for the determination of the differential leakage factor for both symmetrical and asymmetrical full and dead-coil windings of electrical machines. The method can be applied to all multiphase windings and considers Gorges polygons in conjunction with masses geometry in order to find an easy and affordable way to compute the differential leakage factor, avoiding the adoption of traditional methods that refer to the Ossanna's infinite series, which has to be obviously truncated under the bound of a predetermined accuracy. Moreover, the method described in this paper allows the easy determination of both the minimum and maximum v…
Determination of differential leakage factors in electrical machines with non-symmetrical full and dead-coil windings
2017
In this paper Gorges polygons are used in conjunction with masses geometry to find an easy and affordable way to compute the differential leakage factor of non symmetrical full and dead coil winding. By following the traditional way, the use of the Ossanna's infinite series which has to be obviously truncated under the bound of a predetermined accuracy is mandatory. In the presented method no infinite series is instead required. An example is then shown and discussed to demonstrate practically the effectiveness of the proposed method.
Maximum Torque Per Ampere control algorithm for low saliency ratio interior permanent magnet synchronous motors
2017
This paper presents an investigation on the comparison between the Maximum Torque Per Ampere (MTPA) and the Field Orientation Control (FOC) algorithms for interior permanent magnet synchronous machines (IPMSMs). In particular, this study was carried out on a small-power IPMSM with low salience ratio. Both control algorithms have been implemented in the Matlab/Simulink environment, obtaining promising results.
Rivalry of diffusion, external field and gravity in micro-convection of magnetic colloids
2019
Magnetic fields and magnetic materials have promising microfluidic applications. For example, magnetic micro-convection can enhance mixing considerably. However, previous studies have not explained increased effective diffusion during this phenomenon. Here we show that enhanced interface smearing comes from a gravity induced convective motion within a thin microfluidic channel, caused by a small density difference between miscible magnetic and non-magnetic fluids. This motion resembles diffusive behavior and can be described with an effective diffusion coefficient. We explain this with a theoretical model, based on a dimensionless gravitational Rayleigh number, and verify it by numerical si…
Thermal- and photo-induced spin crossover in the 1D coordination polymer [Fe(4-tBupy)3][Au(CN)2]2 (4-tBupy = 4-tert-butylpyridine)
2021
Reaction of the unidentate pyridine ligand containing a bulky t-butyl substituent with Fe2+ and [Au(CN)2]− affords a new type of spin crossover (SCO) coordination polymer in the 1D compound [Fe(4-tBupy)3][Au(CN)2]2⋅0.5H2O (1), which is formed by chains of Fe(II) complexes linked through bridging [Au(CN)2]− with three terminal 4-tBupy and one monodentate [Au(CN)2]− ligands completing the octahedral coordination around Fe(II). Longer reaction times led to the minor products [Fe(4-tBupy)2][Au(CN)2]2 (2), which presents a 2D structure more similar to that found in the other SCO compounds based on [Au(CN)2]−, and the 1D compound [Fe(4-tBupy)2(MeOH)][Au(CN)2]2 (3), in which one of the three termi…
Intrinsic nanostructures on the (001) surface of strontium titanate at low temperatures
2020
Atomically smooth (001) surfaces of SrTiO3 cut from the high-quality single crystals at two different miscut angles 0.9 and 7.0 deg between the real flat surfaces and crystallographic planes (001) were analyzed by means of the reflection high energy electron diffraction (RHEED) method from the room down to liquid helium temperatures. The diffraction patterns typical of the RHEED geometry close to ideal for a small miscut angle and those exhibiting distinct features of the specific periodicity associated with regular steps, which form due to the larger miscut angle, are presented. The surface symmetry and energetics were shown to impose differences in lattice parameters in parallel to a surf…