Search results for "transition"
showing 10 items of 3988 documents
Photocatalytic coalescence of functionalized gold nanoparticles.
2009
A novel strategy for the synthesis of chromophore-functionalized AuNPs with a narrow size distribution is reported. It consists of increasing the size of preprepared NPs by means of a fast (second scale) and clean (light and an organic photocatalyst) method. The results agree with thiolate ligand liberation from the NP surface promoted by photogenerated radicals. This lets gold cores come together and finally coalesce.
Understanding color vision, with comments on mind and matter
2012
Much is known about the mental and physical aspects of color vision. Color vision, therefore, is a paradigm well suited for the discussion of the relationship between mind and matter. The aim of the present chapter is to support the proposition that mental affairs cannot be adequately understood if their neurobiological aspects are neglected. Although it is possible to focus on fundamental problems of general relevance when discussing mind and matter, this chapter will deal with specific observations rather than general issues. The possibility of generalizations derived from empirical results is always limited. Provided the conditions under which these observations were made can be confirme…
1. Recognition And Social Ontology: An Introduction
2011
One of Hegel's big ideas is that creatures with a self-conception are the subjects of developmental processes that exhibit a distinctive structure. Call a creature 'essentially self-conscious' if what it is for itself, its self- conception, is an essential element of what it is in itself. How something that is essentially self-conscious appears to itself is part of what it really is. This chapter shows how the tripartite account of erotic awareness can be used in a natural way to build a notion of recognition that satisfies these twin philosophical constraints on the interpretation of Hegel's notion of self-consciousness in terms of recognition. Doing so it clarifies the nature of the trans…
Human behaviour, benign or malevolent: understanding the human psyche, performing therapy, based on affective mentalization and Matte-Blanco’s bi-log…
2016
International audience; The key concept of Ignacio Matte Blanco’s bi-logic is the unavoidable but variable presence of primary process (symmetric thought) in the secondary one (asymmetric thought) ruling consciousness, for every human being. This variable and dynamic presence allows us, by therapeutic intervention, to convert suitably the symmetric thought into the asymmetric one. The former erupts into the latter by means of affectivity which, accordingly, should be suitably treated to be rightly modulated, regulated and symbolically represented to accomplish the aims of secondary process. This transition has been termed affective mentalization by Peter Fonagy et al. Accordingly, any thera…
Ultrafast dynamics of halogens in rare gas solids
2007
We perform time resolved pump-probe spectroscopy on small halogen molecules ClF, Cl2, Br2, and I2 embedded in rare gas solids (RGS). We find that dissociation, angular depolarization, and the decoherence of the molecule is strongly influenced by the cage structure. The well ordered crystalline environment facilitates the modelling of the experimental angular distribution of the molecular axis after the collision with the rare gas cage. The observation of many subsequent vibrational wave packet oscillations allows the construction of anharmonic potentials and indicate a long vibrational coherence time. We control the vibrational wave packet revivals, thereby gaining information about the vib…
The effect of the internal architecture of polymer micronetwork colloids on the dynamics in highly concentrated dispersions
2007
Motivated by the finding that colloidal dispersions of polymer micronetwork spheres with a cross-link density of 1:50 (inverse number of monomer units between crosslinks) show significant deviations from the dynamics of hard spheres in the colloid glass as seen by dynamic light scattering (DLS) (E. Bartsch, V. Frenz, H. Sillescu J. Non — Cryst. Solids 172–174 (1994), 88–97), we have undertaken a systematic study of the effect of the crosslink density on the dynamics at high concentrations. Long-time self-diffusion coefficients D S L and collective diffusion coefficients D c were measured for colloids with crosslink densities of 1:10, 1:20 and 1:50 by forced Rayleigh scattering (FRS) and the…
Wedge filling and interface delocalization in finite Ising lattices with antisymmetric surface fields
2003
Theoretical predictions by Parry et al. for wetting phenomena in a wedge geometry are tested by Monte Carlo simulations. Simple cubic $L\ifmmode\times\else\texttimes\fi{}L\ifmmode\times\else\texttimes\fi{}{L}_{y}$ Ising lattices with nearest neighbor ferromagnetic exchange and four free $L\ifmmode\times\else\texttimes\fi{}{L}_{y}$ surfaces, at which antisymmetric surface fields $\ifmmode\pm\else\textpm\fi{}{H}_{s}$ act, are studied for a wide range of linear dimensions $(4l~Ll~320,30l~{L}_{y}l~1000),$ in an attempt to clarify finite size effects on the wedge filling transition in this ``double-wedge'' geometry. Interpreting the Ising model as a lattice gas, the problem is equivalent to a li…
Order-disorder phase transition in random-walk networks
2004
In this paper we study in detail the behavior of random-walk networks (RWN's). These networks are a generalization of the well-known random Boolean networks (RBN's), a classical approach to the study of the genome. RWN's are also discrete networks, but their response is defined by small variations in the state of each gene, thus being a more realistic representation of the genome and a natural bridge between discrete and continuous models. RWN's show a clear transition between order and disorder. Here we explicitly deduce the formula of the critical line for the annealed model and compute numerically the transition points for quenched and annealed models. We show that RBN's and the annealed…
Urban gardens and institutional fences: The case of communal gardens in Turin
2017
Urban gardens take on different forms and meanings, which vary depending on the socio-economic context where they located/used and how it evolves over time. This makes a garden comparable to a micro-social ecosystem, different from other gardens and ever changing. As with every social-ecosystem resulting from a territorialisation process, there is a certain degree of social inertia that makes it difficult for outsiders with new motivations and demanding new spaces to enter into the "garden ecosystem". Drawing on existing literature and fieldwork in two urban communal gardens in Turin, the paper is mainly concerned with the spatiotemporal dimension of urban gardening, with a special focus on…
A longitudinal examination of the transition to symbolic communication in the second year of life
2003
Between 10 and 24 months of age, children progress from communicating through conventional signals to communicating through symbols in a variety of situations. The present study investigates this transition analysing mother–child communication frames and the child’s communicative acts, and tracing the developmental changes in both frames and communicative acts. Four children (2 girls, 2 boys) and their mothers were observed longitudinally and extensively, from 10 to 24 months of age, using a multiple case-study method. Through the detailed investigation of these single cases, clear developmental trajectories were found, showing that conventional frames and representational gestures ‘bridge’…