Search results for "transitions"
showing 10 items of 251 documents
High-Pressure Properties of Wolframite-Type ScNbO4
2022
In this work, we used Raman spectroscopic and optical absorption measurements and first-principles calculations to unravel the properties of wolframite-type ScNbO4 at ambient pressure and under high pressure. We found that monoclinic wolframite-type ScNbO4 is less compressible than most wolframites and that under high pressure it undergoes two phase transitions at ∼5 and ∼11 GPa, respectively. The first transition induces a 9% collapse of volume and a 1.5 eV decrease of the band gap energy, changing the direct band gap to an indirect one. According to calculations, pressure induces symmetry changes (P2/c–Pnna–P2/c). The structural sequence is validated by the agreement between phonon calcul…
Single crystal X-ray diffraction studies on [(CH3)nNH4–n]3[Sb2Cl9] (2,3) chloroantimonates(III) in their low-temperature ferroelectric phases—structu…
2005
The structures of two ferroic chloroantimonates(III): [(CH3)2NH2]3[Sb2Cl9] (DMACA) and [(CH3)3NH]3[Sb2Cl9] (TMACA) were determined in their low-temperature phases. The structure of DMACA was investigated at 100 and 15 K, and TMACA at 15 K. The structures consist of two-dimensional inorganic layers and organic cations bound together by the N(C)–H⋯Cl hydrogen bonds. All of the organic cations in both compounds at all studied temperatures are ordered. There is no indication of the structural phase transition in the structure of DMACA below 242 K. The geometry and distortions of the [SbCl6]3– octahedra in both compounds is discussed.
Structure and phase transitions in ethylenediammonium dichloride and its salts with antimony trichloride
2000
During the mixing of ethylenediammonium dichloride and antimony trichloride except of reported earlier [NH3(CH2)2NH3]5(Sb2Cl11)2 · 4 H2O a new salt [NH3(CH2)2NH3](SbCl4)2 was obtained. The crystals are monoclinic at 295 K, space group C2/m, a = 13.829(3), b = 7.408(1), c = 7.588(2) Å; β = 103.18(3)°; V = 756.9(3) Å3; Z = 2; dc = 2.585, dm = 2.56(2) g · cm–3. The structure consists of anionic sublattice built of Sb2Cl82– units composed of two SbCl52– square pyramids connected by edge. The ethylenediammonium cations are located in anionic cavities. The cations are disordered. Each methylene carbon atom is split between two positions. The X‐ray diffraction, DSC, TGA and dilatometric methods we…
The significance of student voice: female students’ interpretations of failure in Tanzanian secondary education
2014
Abstract: In Tanzania, the national examinations are used as the primary tools for selection and transition from lower to upper secondary education. Female students are more likely to fail in the national exams and to drop out from education. This article examines the perspectives of female students concerning their advancement in secondary education. Two sets of qualitative data, responses to a research questionnaire from 100 female lower secondary school students and follow-up interviews with seven mature students enrolled in a non-formal school who had failed in the national examinations, were analysed to identify critical issues influencing the educational advancement of female students…
Children’s transitions in early childhood education and care : various combinations of dis-/continuities
2023
This longitudinal multiple case study explores children’s transitions within early childhood education and care (ECEC) in Finland. In ECEC children typically transition from one group or center to another. This study explores how physical, social and philosophical discontinuities and continuities constitute these transitions. Five focus children’s transitions were followed in and between separate ECEC centers. The data include interviews with parents and educators as well as observations noted. Fabian’s discontinuity division, which argues that transition consists of physical, social, and philosophical discontinuities, was used for content analysis of interviews as primary data. Interpretat…
β-decay rates of 115,117Rh into 115,117Pd isotopes in the microscopic interacting boson-fermion model
2020
The structure of odd-A 115,117Rh and 115,117Pd isotopes is studied by means of the neutron-proton interacting boson-fermion model (IBFM-2). JP=12+ quantum number assignment for the 115,117Pd ground states is critically discussed and the predicted energy levels are compared to the existing experimental data. The resulting nuclear wave functions are used to compute the β-decay ft values of the transitions from 115,117Rh to 115,117Pd in the microscopic IBFM-2 and the results compared with the data. peerReviewed
Chirality of 135 Nd reexamined : Evidence for multiple chiral doublet bands
2019
One new pair of positive-parity chiral doublet bands have been identified in the odd-A nucleus 135Nd which together with the previously reported negative-parity chiral doublet bands constitute a third case of multiple chiral doublet (MχD) bands in the A ≈ 130 mass region. The properties of the MχD bands are well reproduced by constrained covariant density functional theory and particle rotor model calculations. The newly observed MχD bands in 135Nd represents an important milestone in supporting the existence of MχD in nuclei. peerReviewed
Restoring the valence-shell stabilization in 140Nd
2020
A projectile Coulomb-excitation experiment was performed at the radioactive-ion beam facility HIE-ISOLDE at CERN to obtain $E2$ and $M1$ transition matrix elements of $^{140}$Nd using the multistep Coulomb-excitation code GOSIA. The absolute $M1$ strengths, $\textrm{B}(M1;2^+_2→2^+_1)=0.033(8)μ^2_N,\textrm{B}(M1;2^+_3→2^+_1)=0.26^{+0.11}_{−0.10}μ^2_N$, and $\textrm{B}(M1;2^+_4→2^+_1)<0.04μ^2_{\textrm{N}}$, identify the $2^+_3$ state as the main fragment of the one-quadrupole-phonon proton-neutron mixed-symmetry state of $^{140}$Nd. The degree of F-spin mixing in $^{140}$Nd was quantified with the determination of the mixing matrix element $V_{\textrm{F−mix}}<7^{+13}_{−7}$keV.
Spin-dependent evolution of collectivity in 112Te
2017
The evolution of collectivity with spin along the yrast line in the neutron-deficient nucleus 112Te has been studied by measuring the reduced transition probability of excited states in the yrast band. In particular, the lifetimes of the 4+ and 6+ excited states have been determined by using the recoil distance Doppler-shift method. The results are discussed using both large-scale shell-model and total Routhian surface calculations. peerReviewed
Competition between allowed and first-forbidden β decays of At208 and expansion of the Po208 level scheme
2021
The structure of 208Po populated through the EC/β+ decay of 208At is investigated using γ-ray spectroscopy at the ISOLDE Decay Station. The presented level scheme contains 27 new excited states and 43 new transitions, as well as a further 50 previously observed γ rays which have been (re)assigned a position. The level scheme is compared to shell model calculations. Through this analysis approximately half of the β-decay strength of 208At is found to proceed via allowed decay and half via first-forbidden decay. The first-forbidden transitions predominantly populate core excited states at high excitation energies, which is qualitatively understood using shell model considerations. This mass r…