Search results for "ultrasonics"

showing 10 items of 326 documents

The ultrasounds-ionic liquids synergy on the copper catalyzed azide-alkyne cycloaddition between phenyl acetylene and 4-azidoquinoline

2015

Abstract The effect of ultrasound irradiation on the copper catalyzed azide–alkyne cycloaddition between phenylacetylene and 4-azidoquinoline has been studied in solution of different ionic liquids. In particular, we used ionic liquids featuring both aliphatic and aromatic mono- and dications, as well as anions differing in size, symmetry and coordination ability. We also examined the influence of the ionic liquids structural features on the reaction outcomes, finding that under magnetic stirring reactivity is favorably affected by the solvent structural organization, while under sonochemical conditions an opposite trend was observed. In all cases examined, sonochemical activation leads to …

chemistry.chemical_classificationAcoustics and UltrasonicsChemistryOrganic ChemistryAlkyneSettore CHIM/06 - Chimica Organicaequipment and suppliesPhotochemistryCycloadditionInorganic ChemistrySolventchemistry.chemical_compoundPhenylacetyleneIonic liquidCopper catalyzedChemical Engineering (miscellaneous)Environmental ChemistryRadiology Nuclear Medicine and imagingReactivity (chemistry)AzideIonic liquids Ultrasound irradiation Azide-alkyne cycloaddition
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Effective conductivity in association with model structure and spatial inhomogeneity of polymer/carbon black composites

1996

The relationship between effective conductivity and cell structure of polyethylene/carbon composites as well as between effective conductivity and spatial distribution of carbon black are discussed. Following Yoshida's model both structures can, in a way, be said to be intermediate between the well known Maxwell-Garnett (MG) and Bruggeman (BR) limiting structures. Using TEM photographs on composites with various carbon blacks we have observed that the larger is Garncarek's inhomogeneity measure H of two-dimensional (2D) representative distribution of the carbon black, the smaller is the effective conductivity of the composite.

chemistry.chemical_classificationCondensed Matter - Materials ScienceMaterials scienceAcoustics and UltrasonicsComposite numberMaterials Science (cond-mat.mtrl-sci)FOS: Physical scienceschemistry.chemical_elementCarbon blackPolymerConductivityPolyethyleneCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryCarbon compositesCell structureComposite materialCarbonJournal of Physics D: Applied Physics
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Iodine and mercury resonance lamps for kinetics experiments and their spectra in the far ultraviolet

2000

Electrodeless iodine and mercury iodide radio-frequency discharge lamps have been made to provide intense sources of resonance radiation of iodine and mercury in the 183-253 nm region. Production technology and emission spectra in the ultraviolet and vacuum ultraviolet regions are described. Both lamps (iodine and mercury iodide) are designed and used for monitoring the iodine 2P1/2 (206.163 nm) and 2P3/2 (183.038 nm) level population kinetics after flash photolysis of I2 or other precursor molecules in laboratory experiments. The technique is suitable for the investigation of the gas phase reaction kinetics following the photolysis of I2 in the presence of O3.

chemistry.chemical_classificationGas-discharge lampAcoustics and UltrasonicsKineticsPhotodissociationIodideAnalytical chemistrychemistry.chemical_elementCondensed Matter PhysicsIodinemedicine.disease_causeSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialslaw.inventionMercury (element)chemistrylawmedicineFlash photolysisUltravioletJournal of Physics D: Applied Physics
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Bimodal Effect of Amphiphilic Biocide Concentrations on Fluidity of Lipid Membranes

1996

Abstract Using the spin label method (ESR) it has been shown that biologically active, amphiphilic compounds (quaternary ammonium salts -AS) containing polar heads with single and double positive charge caused, at low concentrations, decrease fluidity of liposome membranes formed with egg yolk lecithin (EYL). At higher concentrations an increase in fluidity was observed. With compounds having a single positive charge minimum fluidity of membrane structure occurs in the range of 1 to 3%, with compounds containing double positive charge -in the range of 4 -6 % . That effect does not depend on polar head size and length of alkyl chains of the AS used. Analysis of the electrostatic interaction …

chemistry.chemical_classificationLiposomefood.ingredientMembrane FluidityBinding energyInorganic chemistryElectron Spin Resonance SpectroscopyEgg YolkModels BiologicalLecithinGeneral Biochemistry Genetics and Molecular BiologyDivalentCyclic N-OxidesQuaternary Ammonium CompoundsMembranefoodchemistryBiochemistryLiposomesPhosphatidylcholinesMembrane fluiditySpin LabelsUltrasonicsSpin labelAlkylZeitschrift für Naturforschung C
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Amorphous polyphosphate nanoparticles: application of the morphogenetically active inorganic polymer for personalized tissue regeneration

2019

chemistry.chemical_compoundInorganic polymerAcoustics and UltrasonicschemistryChemical engineeringPolyphosphateNanoparticleCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsAmorphous solidJournal of Physics D: Applied Physics
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Tailoring the excitation of fundamental flexural guide waves in coated bone by phase-delayed array: Two-dimensional simulations

2015

The fundamental flexural guided wave (FFGW) enables ultrasonic assessment of cortical bone thickness. In vivo, it is challenging to detect this mode, as its power ratio with respect to disturbing ultrasound is reduced by soft tissue covering the bone. A phase-delayed ultrasound source is proposed to tailor the FFGW excitation in order to improve its power ratio. This situation is analyzed by 2D finite-element simulations. The soft tissue coating (7-mm thick) was simulated as a fluid covering an elastic plate (bone, 2–6 mm thick). A six-element array of emitters on top of the coating was excited by 50-kHz tone bursts so that each emitter was appropriately delayed from the previous one. Respo…

fundamental flexural guided wavesGuided wave testingMaterials scienceAcoustics and Ultrasonicsta114business.industryultrasoundPhase (waves)engineering.materialmedicine.anatomical_structureOpticsLamb wavesArts and Humanities (miscellaneous)Coatingcortical bone thicknessmedicineengineeringCortical boneUltrasonic sensorbusinessExcitationCommon emitterta217Journal of the Acoustical Society of America
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A social survey on the effects of environmental noise on the residents of Pamplona, Spain

1998

Abstract An extensive noise survey carried out in the city of Pamplona, Spain over 2 years has allowed us to elaborate a detailed daytime acoustic map of this city. The degree of noise annoyance in the community and its relationship with the measured noise levels has also been studied by means of a social survey.

geographyGeneral Social SurveyNoisegeography.geographical_feature_categoryAcoustics and UltrasonicsEnvironmental engineeringUrban noiseEnvironmental noiseSocioeconomicsUrban areaNoise annoyanceResidential areaApplied Acoustics
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Temporal loudness weights in background noise: Data and models

2019

Previous studies consistently showed that human listeners primarily consider the beginning of a time-varying sound when judging its overall loudness, and place less weight on subsequent temporal portions. However, all experiments studying this primacy effect in temporal loudness weights presented the target sound in quiet. Here, we compared temporal weights when the target sound was either presented in quiet or in a continuous background noise, and for a variation in the level of the target sound across a range of 60 dB. The target sound was a time-varying narrowband noise, the background noise was a continuous bandpass-filtered noise. In all conditions, we observed the expected primacy eff…

geographygeography.geographical_feature_categoryAcoustics and UltrasonicsAcousticsLoudnessBackground noiseNoiseArts and Humanities (miscellaneous)QUIETRange (statistics)Exponential decayNarrowband noiseSound (geography)MathematicsThe Journal of the Acoustical Society of America
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Inspection of laser powder deposited layers

2013

laser powder deposition laser ultrasonics eddy current
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Time of flight for photon in human skin

2016

The time of flight for photons in human skin was measured using picosecond diode laser. Two different wavelength lasers were used - 405 nm and 510 nm. A difference for time of flight in normal skin and in nevus was observed as well as a difference for different wavelength laser irradiation was observed. For 405 nm laser irradiation the difference was 41 ps while comparison of time of flights skin and nevi using 510 nm irradiation showed a result of 32 ps. Results allow to conclude that the time photon travels in skin might depend on the characteristics of the medium and wavelength of the irradiation. This can be related to known data for light penetration depth in human skin for different w…

lcsh:Applied optics. PhotonicsMaterials sciencelcsh:Medical technologyAcoustics and UltrasonicsBiomedical EngineeringHuman skinmedical physicslaw.inventionBiomaterialsOpticslawIrradiationAbsorption (electromagnetic radiation)integumentary systembusiness.industrybiophotonicslcsh:TA1501-1820absorbtionLaserAtomic and Molecular Physics and OpticsBiophotonicsTime of flightWavelengthlight impulselcsh:R855-855.5PicosecondOptoelectronicsbusinessJournal of Biomedical Photonics & Engineering
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