Search results for "unitary transformation"
showing 4 items of 14 documents
Interaction between strong radiation fields and two-level atoms: A canonical transformation approach
2008
Triangular mass matrices of quarks and Cabibbo-Kobayashi-Maskawa mixing
1998
Every nonsingular fermion mass matrix, by an appropriate unitary transformation of right-chiral fields, is equivalent to a triangular matrix. Using the freedom in choosing bases of right-chiral fields in the minimal standard model, reduction to triangular form reduces the well-known ambiguities in reconstructing a mass matrix to trivial phase redefinitions. Furthermore, diagonalization of the quark mass sectors can be shifted to one charge sector only, without loosing the concise and economic triangular form. The corresponding effective triangular mass matrix is reconstructed, up to trivial phases, from the moduli of the CKM matrix elements, and vice versa, in a unique way. A new formula fo…
Quasi diabatic CASSCF state functions
2002
A new method to determine quasi diabatic (QD) CASSCF states is presented. The adiabatic states are subjected to a unitary transformation resulting from diagonalization of a state-selection operator. The latter is constructed from the overlap of the adiabatic states with a suitable set of reference states. The multi-state (MS) CASPT2 method is used to account for the dynamical correlation effects in an approach where the QD-CASSCF wave functions are used as reference states. The procedure is applied to avoided crossings in excited states of BeH, LiO and ozone. The advantages of the proposed formulation are discussed.
Unitary transformations depending on a small parameter
2011
We formulate a unitary perturbation theory for quantum mechanics inspired by the LieDeprit formulation of canonical transformations. The original Hamiltonian is converted into a solvable one by a transformation obtained through a Magnus expansion. This ensures unitarity at every order in a small parameter. A comparison with the standard perturbation theory is provided. We work out the scheme up to order ten with some simple examples.