Search results for "upconversion"
showing 10 items of 54 documents
Infrared to visible upconversion luminescence properties in the system Ln2BaZnO5 (Ln=La, Gd)
2009
Abstract We have investigated the upconversion properties of the rare-earth doped systems La 2 BaZnO 5 ( I 4/ mcm ) and Gd 2 BaZnO 5 ( Pbnm ). The dependence of the luminescence properties on the identity and the concentration of the dopants, Er 3+ and Er 3+ co-doped with Yb 3+ , as well as on the synthetic route, was examined. Following coherent excitation at 975 nm, strong upconversion emission was observed in the visible region (525, 550 and 660 nm). Power dependence studies revealed a two photon process for these emissions. In the co-doped samples, a blue emission (410 nm) could also be observed. For this emission, the power dependence studies confirmed a three photon process.
Initial Biological Assessment of Upconversion Nanohybrids
2021
Nanoparticles for medical use should be non-cytotoxic and free of bacterial contamination. Upconversion nanoparticles (UCNPs) coated with cucurbit[7]uril (CB[7]) made by combining UCNPs free of oleic acid, here termed bare UCNPs (UCn), and CB[7], i.e., UC@CB[7] nanohybrids, could be used as photoactive inorganic-organic hybrid scaffolds for biological applications. UCNPs, in general, are not considered to be highly toxic materials, but the release of fluorides and lanthanides upon their dissolution may cause cytotoxicity. To identify potential adverse effects of the nanoparticles, dehydrogenase activity of endothelial cells, exposed to various concentrations of the UCNPs, was determined. Da…
Dynamic Characterization of Upconversion in Highly Er-Doped Silica Photonic Crystal Fibers
2012
Measurements of time evolution of amplified spontaneous emission for square-wave modulated pump were made on a highly erbium-doped silica photonic crystal fiber and fitted to theoretical results calculated using different formalisms to describe the ${\rm Er}^{3+}$ -ion migration-assisted co-operative upconversion mechanism in the population densities rate equations. The determined characterization parameters are the constant homogeneous upconversion coefficient, 3.0 $\times 10^{-24}~{\rm m}^{3}/{\rm s}$ , the critical radii for upconversion and migration, 10.5 and 14A, respectively, and the rate of clustered ions, 14%. These parameters are analysed and compared to those obtained with contin…
Ultrafast broadband fluorescnce up-conversion of N-acetyl-L-tryptophanamide (NATA)
2011
Estrategia para estabilización de nanopartículas de upconversion en medios acuosos y su excitación a 800 nm
2020
Actualmente existe una importante variedad de métodos sintéticos para la preparación de UCNPs, los cuales permiten controlar parámetros tales como tamaño, forma o fase de las UCNPs. A pesar de ello, la estabilidad del recubrimiento de las UCNPs en medios acuosos y, principalmente, en medios ácidos es una de las limitaciones para su uso en diversas aplicaciones biológicas o tecnológicas. Además, la longitud de onda de excitación NIR de la UCNP es relevante cuando se utilizan disoluciones acuosas, ya que la absorción del agua a 980 nm filtra la absorción del Yb3+ y causa calentamiento de la muestra, lo que es particularmente nocivo para muestras biológicas. La solución aportada en la bibliogr…
Linear Coassembly of Upconversion and Perovskite Nanoparticles: Sensitized Upconversion Emission of Perovskites by Lanthanide‐Doped Nanoparticles
2020
Sensitized emission of lead halide perovskite nanoparticles (LHPNPs) can be achieved by near‐infrared (NIR) excitation of nearby lanthanide‐doped upconversion nanoparticles (UCNPs) by using a low‐cost diode laser. Here, the first preparation of linear assemblies of core and core–shell NPs, as well as linear coassemblies of LHPNPs and UCNPs, within an open peapod‐like lead sulfate shell are reported. UCNPs with a NaYF4 matrix doped with ytterbium and thulium or erbium, and with an inert shell of NaYF4 in the case of core‐shell, and all‐inorganic CsPbX3 NPs (X = halide) are chosen for these studies. Interestingly, the lead sulfate shell enhances the luminescence of the core/core– shell UCNPs …
Near-IR to Near-IR Upconversion Luminescence in Molecular Chromium Ytterbium Salts
2020
Abstract Upconversion photoluminescence in hetero‐oligonuclear metal complex architectures featuring organic ligands is an interesting but still rarely observed phenomenon, despite its great potential from a basic research and application perspective. In this context, a new photonic material consisting of molecular chromium(III) and ytterbium(III) complex ions was developed that exhibits excitation‐power density‐dependent cooperative sensitization of the chromium‐centered 2E/2T1 phosphorescence at approximately 775 nm after excitation of the ytterbium band 2F7/2→2F5/2 at approximately 980 nm in the solid state at ambient temperature. The upconversion process is insensitive to atmospheric ox…
Single photon MIR upconversion detector at room temperature with a PPLN ridge waveguide
2019
International audience; In this paper we describe an upconversion detector in the mid infrared (around 3.5 μm). We take advantage of the PPLN ridge waveguide technology to achieve single photon detection at room temperature on a single spatial mode. With a pump power of 192 mW we obtain a detection efficiency of 0.4% for 22k dark count per second, which corresponds to a noise equivalent power of 3.0 fW · Hz−1/2 and an internal conversion efficiency of 85 %/W of pump.
Inorganic Protection of Polymer Nanocapsules: A Strategy to Improve the Efficiency of Encapsulated Optically Active Molecules
2018
Functional Nanohybrids Based on Dyes and Upconversion Nanoparticles
2020
Upconversion nanoparticles (UCNPs) and dyes are combined to make nanohybrid systems, which take advantage of the synergic relationship between lanthanide (Ln)-based UCNPs and dyes. Ln-UCNPs are inorganic nanophosphors which absorb NIR light and emit narrow emission bands in the UV-NIR region with long luminescence lifetimes. These unique properties, when coordinated properly with dyes of the appropriate photophysical features, produce nanosystems with new photophysical properties. In this context, the UCNP-dye nanohybrids are very promising for potential sensing (ions and biomolecules) and theragnosis (imaging and therapy, e.g. photodynamic therapy).