Search results for "valorization"

Energy harvesting by waste acid/base neutralization via bipolar membrane reverse electrodialysis

2020

Bipolar Membrane Reverse Electrodialysis (BMRED) can be used to produce electricity exploiting acid-base neutralization, thus representing a valuable route in reusing waste streams. The present work investigates the performance of a lab-scale BMRED module under several operating conditions. By feeding the stack with 1 M HCl and NaOH streams, a maximum power density of ~17 W m−2 was obtained at 100 A m−2 with a 10-triplet stack with a flow velocity of 1 cm s−1, while an energy density of ~10 kWh m−3 acid could be extracted by a complete neutralization. Parasitic currents along feed and drain manifolds significantly affected the performance of the stack when equipped with a higher number of t…

Neutralization of acid and base solutions by Reverse Electrodialysis with Bipolar Membranes: a sustainable way to recover energy

2020

The large amount of acidic wastewaters produced in various industrial processes can have a large economic and environmental impact. Companies producing waste acid solutions have to send them to specific sites for the neutralization with alkaline solutions. However, efforts have been devoted so far to promote the acid recovery or its reuse. In the perspective of a more circular manufacturing approach, the present work proposes for the first time the use of the novel Bipolar Membrane Reverse Electrodialysis technology as a viable on-site way to convert the chemical energy associated to the pH gradient of waste acid/base solutions into electrical energy. Bipolar Membrane Reverse Electrodialysi…

Conversion of carbohydrates into 5-HMF in Deep Eutectic Solvents under mild reaction conditions

Rosticceria: ibridazioni gustative e logiche identitarie

2020

this contribution is dedicated to the analysis of a particular dish of sicilian, and in particular palermitan, cuisine known as 'rosticceria'. the essay investigates the ambivalent status of such bread dough-based dishes, halfway between street food and other categories of dishes. the analysis concerns both the manner and timing of consumption and the food-object itself from the point of view of its gustatory and sensory characteristics.

Chemical Composition, In Vitro Bioaccessibility and Antioxidant Activity of Polyphenolic Compounds from Nutraceutical Fennel Waste Extract

2021

Fennel (Foeniculum vulgare Mill.) waste contains a broad range of bioactive molecules, including polyphenols, which have poor bioaccessibility during gastrointestinal digestion. This work aimed to investigate the bioaccessibility of total phenolic compounds and the antioxidant capacity during simulated gastrointestinal digestion using two nutraceutical formulations based on non-acid-resistant (NAR) and acid-resistant (AR) capsules containing aqueous-based extracts from fennel waste. Moreover, to obtain a comprehensive investigation of the polyphenolic constituents of the fennel waste extract, a high-resolution mass spectrometry (Q-Orbitrap) analysis was performed. Notably, chlorogenic acids…

Slow Pyrolysis come metodo per la valorizzazione di rifiuti e biomassa residuale

2022

Amino acid-based cholinium ionic liquids as sustainable catalysts for pet depolymerization

2021

Chemical recycling to monomers is one of the key strategies in tackling the issues deriving from persistent plastic pollution in the environment, and poly(ethylene terephthalate) (PET) is among the most used polymers in modern society. In this context, we herein describe the glycolysis of PET to bis-hydroxyethyl terephthalate (BHET), promoted by basic cholinium salts differing for the anions, also comprising amino acid anions. We investigated the optimal reaction conditions, finding that the best-performing catalyst is [Ch][Gly], in the presence of which a conversion of 85% and a yield of 51% are achieved at 150 °C after 6 h, from PET deriving from a clear water bottle. We used our protocol…

RELATION BETWEEN ROW AND LEAF ORIENTATION OF SYRAH/101-14 MGT

2011

Creative Tourism. Connecting Fontanelle Cemetery to a Larger Touristic Route

2021

The case study of this paper concerned the Fontanelle cemetery, an underground site with a long and peculiar history shaped by its origin, use and function as well as from its location, Rione Sanità. This area is a popular neighbourhood of Naples with original characteristics and challenges that we tried to learn, understand, and approach. The task of this work was to develop a strategy to connect the site to a larger touristic route through the implementation of Creative Tourism approaches.

Highly-Efficient Release of Ferulic Acid from Agro-Industrial By-Products via Enzymatic Hydrolysis with Cellulose-Degrading Enzymes: Part I–The Super…

2021

Historically Triticum aestívum L. and Secale cereále L. are widely used in the production of bakery products. From the total volume of grain cultivated, roughly 85% is used for the manufacturing of flour, while the remaining part is discarded or utilized rather inefficiently. The limited value attached to bran is associated with their structural complexity, i.e., the presence of cellulose, hemicellulose, and lignin, which makes this material suitable mostly as a feed supplement, while in food production its use presents a challenge. To valorize these materials to food and pharmaceutical applications, additional pre-treatment is required. In the present study, an effective, sustainable, and …