Search results for "visual"

S734 LIGHT HELPS IN VISUALIZATION AND CONTROL OF SYMPATHETIC BLOCKS

2011

Autologous conditioned serum for chronic pain in patients with osteoarthritis: A feasibility observational study

2022

Background Autologous conditioned serum is a product of blood origin, with fragmented evidence of therapeutic properties in osteoarthritis chronic pain. This pilot observational prospective study aimed to evaluate the feasibility of a treatment with conditional autologous serum (ACS) in patients with severe chronic pain and grade I-III osteoarthritis and to describe its cytokine content. Methods We prospectively collected data on consecutive patients affected by osteoarthritis grade I to III and treated with four weekly injections of ACS at our outpatient pain service. The primary outcome was pain intensity, measured with the visual analogic scale (VAS). Additional outcomes were symptoms ev…

Animal agency in Iron-Age Sicilian art (VIII-VI BCE): Interaccion between bovines and man

2019

El objetivo del presente artículo es el análisis de las relaciones entre bovinos y humanos bajo la perspectiva de la agencia animal a través de varios objetos artísticos encontrados en el asentamiento de Polizzello (Sicilia occidental), datados entre los ss. VIII-VI a. C. Concretamente, presentamos un conjunto de jarras cerámicas decoradas con bucráneos, así como también representaciones de bovinos y seres híbridos en distintos soportes cerámicos como son vasos de almacenamiento, de consumo y servicio de alimentos. En primer lugar, nos centraremos brevemente en explicar el contexto histórico y social de la isla en la Edad del Hierro, haciendo especial énfasis en sus tradiciones artísticas. …

The influence of temperature on growth and proximate body composition of under yearling Lake Inari arctic char (Salvelinus alpinus (L.))

1997

The growth of underyearling Lake Inari arctic char was studied in groups of fish held at 5.9, 8.7, 12.1, 15.1 and 18.0 °C for 31 days. Growth rate increased with increasing water temperature, reached a peak at 15.1 °C, and then declined. The temperature influence on relative growth was expressed as a non-linear function. There were differences in body composition between fish reared at different temperatures: percentage water being highest at the lowest temperature, whereas energy content was highest in the fish held at the three highest temperatures. The body wet weight explained most of the variance in water content and it is suggested that this may also apply to other body constituents.

Gender influence on body composition in preterm infants fed human milk or preterm formula

1999

Surface charge fine tuning of reversed-phase/weak anion-exchange type mixed-mode stationary phases for milder elution conditions.

2015

A series of new mixed-mode reversed-phase/weak anion-exchange (RP/WAX) phases have been synthesized by immobilization of N-undecenyl-3-α-aminotropane onto thiol-modified silica gel by thiol-ene click chemistry and subsequent introduction of acidic thiol-endcapping functionalities of different type and surface densities. Click chemistry allowed to adjust a controlled surface concentration of the RP/WAX ligand in such a way that a sufficient quantity of residual thiols remained unmodified which have been capped by thiol click with either 3-butenoic acid or allylsulfonic acid as co-ligands. In another embodiment, performic acid oxidation of N-undecenyl-3-α-aminotropane-derivatized thiol-modifi…

[3.3]Ferrocenophanes with guanidine bridging units as multisignalling receptor molecules for selective recognition of anions, cations, and amino acid…

2007

The synthesis, electrochemical, and optical properties of a new [3.3]ferrocenophane framework in which two ferrocene subunits, with similar electronic environments, are linked through two substituted guanidine moieties, are reported. The receptors 4-7 have been prepared in good yields by the reaction of bis(carbodiimide) 3 with primary amines. This architecture is exceptionally "tunable" because a variety of "legs" may be appended to the basic [3.3]ferrocenophane scaffold to give a wide range of signaling units. These receptors show remarkable ion-sensing properties, due to the presence of a redox active unit (ferrocene), and an amphoteric binding site (guanidine). In this nitrogen-rich str…

Synthesis, reactivity, and computational analysis of halophosphines supported by dianionic guanidinate ligands.

2012

The reported chemistry and reactivity of guanidinate supported group 15 elements in the +3 oxidation state, particularly phosphorus, is limited when compared to their ubiquity in supporting metallic elements across the periodic table. We have synthesized a series of chlorophosphines utilizing homo- and heteroleptic (dianionic)guanidinates and have completed a comprehensive study of their reactivity. Most notable is the reluctancy of these four-membered rings to form the corresponding N-heterocyclic phosphenium cations, the tendency to chemically and thermally eliminate carbodiimide, and the scarcely observed ring expansion by insertion of a chloro(imino)phosphine into a P-N bond of the P-N-…

Influence of the anions on the structure and magnetic properties of a series of bis(µ-diphexono)-bridged linear trinuclear copper(II) complexes: an e…

2011

The reaction of H(2)L (N,N'-dimethyl-N,N'-bis(2-hydroxy-3-methoxy-5-methylbenzyl)-ethylenediamine) with different copper salts, in methanol and using a H(2)L/Cu = 2 : 3 molar ratio, led to four new bis(μ-diphenoxo)-bridged Cu(3) complexes of general formula [{Cu(S)(μ-L)}(2)Cu(H(2)O)(2n)]X(2) (S = CH(3)OH, n = 1 and X = BF(4)(-) for (1) or ClO(4)(-) for (2); S = Br(3)(-) anion and n = 1 without any X species for (3); S = H(2)O, n = 0 and X = NO(3)(-) for (4)). The use in the same reaction conditions of 4,4'-bipyridine (4,4'-bipy) as connector led to the chain complex [{Cu(μ-4,4'-bipy)(0.5)(μ-L)}(2)Cu(H(2)O)(2n)](ClO(4))(2)·17H(2)O (5). The structure of the centrosymmetric trinuclear unit in …

Determination of non-ionic and anionic surfactants in industrial products by separation on a weak ion-exchanger, derivatization and liquid chromatogr…

2013

Abstract A method for the determination of priority surfactants, including fatty alcohol ethoxylates (FAE), alkylether sulfates (AES) and linear alkylbenzene sulfonates (LAS) is described. The samples were diluted with 50% methanol at pH 4 prior to solid-phase extraction on a weak anionic exchanger (WAX). The AES and LAS surfactant classes were retained, whereas the non-ionic components, including most FAE oligomers were eluted. After washing the WAX cartridge to remove cations, the remaining hydrophobic FAE oligomers were eluted using hot 80% methanol at pH 4 (at ca. 50 °C). These two eluates were combined to constitute the non-ionic fraction. Then, AES and LAS were eluted using 80% MeOH w…