Search results for "visual_art.visual_art_medium"
showing 10 items of 2982 documents
Mechanical Stresses: Inhibitor of Catalyst of High Temperature Oxidation?
2001
Oxidation of metals is a complex reaction in which mechanical and chemical phenomena occur. A dynamic and macroscopic model is developed in order to simulate oxidation kinetics of a metal. It includes the stress/diffusion coupling in the bulk and the interfacial phenomena at metal/oxide interface. Its application to the Zr/ZrO 2 system shows the important role of stress field distribution in oxide on kinetic behavior. According to the sign of stress gradient in the oxide scale, the oxidation rate can speed up or slow down. The calculated kinetic curves could he fitted using a k p .t 1/n law where n and kp vary all over the process, like for the experimental kinetic curves.
Synthesis and characterization of V2O5SiO2ZrO2 pigments by sol-gel method
1992
Abstract Polymeric gels in the V2O5 SiO2 ZrO2 system were prepared from tetraethylorthosilicate (TEOS), zirconium(IV)-n-propoxide and vanadium(IV) oxyacetylacetonate, precursors. The effects of prehydrolysis time of TEOS and drying gel method on the stabilization of tetragonal zirconia in the silica amorphous matrix, nucleation and growth of the zircon (ZrSiO4) phase, and stabilization of the blue and green stains of vanadium zircon were studied. Results provide evidence that long time of prehydrolysis and fast drying do not favour zircon crystallization but stabilize the tetragonal zirconia in the amorphous matrix.
Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties
2020
The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation pathways. The gap between the metal-centered states is maximal when the coordination sphere of the complex approaches an ideal octahedral geometry. Two new iron(II) complexes (C1 and C2), prepared from pyridylNHC and pyridylquinoline type ligands, respectively, have a near-perfect octahedral coordination of the metal. The photophysics of the complexes have been further investigated by means of ultrafast spectroscopy and TD-DFT modeling. For C1, it is shown that&mdash
“Two-Story” Calix[6]arene-Based Zinc and Copper Complexes: Structure, Properties, and O 2 Binding
2017
International audience; A new “two-story” calix[6]arene-based ligand was synthesized, and its coordination chemistry was explored. It presents a tren cap connected to the calixarene small rim through three amido spacers. X-ray diffraction studies of its metal complexes revealed a six-coordinate ZnII complex with all of the carbonyl groups of the amido arms bound and a five-coordinate CuII complex with only one amido arm bound. These dicationic complexes were poorly responsive toward exogenous neutral donors, but the amido arms were readily displaced by small anions or deprotonated with a base to give the corresponding monocationic complexes. Cyclic voltammetry in various solvents showed a r…
Swarming of micron-sized hematite cubes in a rotating magnetic field -- Experiments
2020
Energy input by under-field rotation of particles drives the systems to emergent non-equilibrium states. Here we investigate the suspension of rotating magnetic cubes. Micron-sized hematite cubes are synthesized and observed microscopically. When exposed to a rotating magnetic field, they form rotating swarms that interact with each other like liquid droplets. We describe the swarming behaviour and its limits and characterize swarm size and angular velocity dependence on magnetic field strength and frequency. A quantitative agreement with a theoretical model is found for the angular velocity of swarms as a function of field frequency. It is interesting to note that hematite particles with p…
Torrefaction and pyrolysis of metal-enriched poplars from phytotechnologies: Effect of temperature and biomass chlorine content on metal distribution…
2017
Abstract Torrefaction (290 °C) and pyrolysis (450 and 800 °C) trials were performed at pilot scale with a patented reactor on metal-enriched poplars from a contaminated soil managed by phytotechnologies and poplars cultivated on uncontaminated soil, for comparison. This study emphasized the influence of temperature on end-product yield, metal distribution in end-products and metal behavior. Results showed that the evolution of the end-product yield, i.e. biochar, bio-oil and gas fractions, was depending on temperature rather than other parameters such as the origin or metal content of the tested poplars. Torrefaction decreased the processed poplars weight, leading to metal-enriched torrefie…
Copper binding capacity of root exudates of cultivated plants and associated weeds
2001
International audience; Cu binding to root exudates of two cultivated plants, wheat (Triticum aestivum) and rape (Brassica napus), and two weeds associated with wheat, dog daisy (Matricaria inodora) and cornflower (Centaurea cyanus), was studied in vitro under hydroponic and sterile conditions. Nutrient solutions were prepared with or without P. A MetPLATE microbiological test was used to assess the metal complexing capacity of root exudates. In the P-deficient solutions, no exudation was observed for any of the four plants; consequently, no Cu binding occurred. When P was present in the nutrient solutions, the plant exudates displayed differing abilities to complex Cu. No difference was de…
Zinc isotopes in Late Pleistocene fossil teeth from a Southeast Asian cave setting preserve paleodietary information
2020
Significance Dietary habits, especially meat consumption, represent a key aspect in the behavior and evolution of fossil hominin species. Here, we explore zinc (Zn) isotope ratios in tooth enamel of fossil mammals. We show discrimination between different trophic levels and demonstrate that Zn isotopes could prove useful in paleodietary studies of fossil hominin, or other mammalian species, to assess their consumption of animal versus plant resources. We also demonstrate the high preservation potential of pristine diet-related Zn isotope ratios, even under tropical conditions with poor collagen preservation, such as the studied depositional context in Southeast Asia. However, assessing the …
Development of Removable Visual Impact Indicator or Polymer Composite Materials
2021
The prototype of removable visual impact indicator for thermoset polymer composite materials is developed, and its characteristics are experimentally determined. The indicator is a fabric tape glued by epoxy to the surface of the polymer composite. The tape is impregnated with a composition that provides a visual response at the place of an impact on the composite surface. Ball-drop tests demonstrated the increase of the magnitude of the visual response with the impact energy at different substrate hardnesses. The shelf-life and mode of the tape storage until commissioning are determined. Peel tests showed the ability to remove a used indicator without damaging the surface of the composite.
A novel linear friction welding based approach for sheet-bulk joining
2019
In the last decades, the development of new, flexible manufacturing processes caused the increase of the demands for highly customized complex functional parts in many industrial fields. The peculiar design of these components often overcome conventional sheet metal and bulk metal forming processes capabilities. In order to face this issue, new hybrid techniques, capable of exploit key advantages of different processes, have to be developed. In this paper, a novel approach based on the Linear Friction Welding process is proposed to obtain sheet-bulk joints. The feasibility of the technique on high specific strength alloys is investigated through an experimental campaign.In the last decades,…