Search results for "visual_art.visual_art_medium"

Metal specificity of the Ni(II) and Zn(II) binding sites of the N-terminal and G-domain of E. coli HypB

2021

HypB is one of the chaperones required for proper nickel insertion into [NiFe]-hydrogenase. Escherichia coli HypB has two potential Ni(II) and Zn(II) binding sites—the N-terminal one and the so-called GTPase one. The metal-loaded HypB–SlyD metallochaperone complex activates nickel release from the N-terminal HypB site. In this work, we focus on the metal selectivity of the two HypB metal binding sites and show that (i) the N-terminal region binds Zn(II) and Ni(II) ions with higher affinity than the G-domain and (ii) the lower affinity G domain binds Zn(II) more effectively than Ni(II). In addition, the high affinity N-terminal domain, both in water and membrane mimicking SDS solution, has a…

Role of Surface Chemistry in the Superhydrophobicity of the Springtail Orchesella cincta (Insecta:Collembola)

2020

Collembola are ancient arthropods living in soil with extensive exposure to dirt, bacteria, and fungi. To protect from the harsh environmental conditions and to retain a layer of air for breathing when submerged in water, they have evolved a superhydrophobic, liquid-repelling cuticle surface. The nonfouling and self-cleaning properties of springtail cuticle make it an interesting target of biomimetic materials design. Recent research has mainly focused on the intricate microstructures at the cuticle surface. Here we study the role of the cuticle chemistry for the Collembola species Orchesella cincta (Collembola, Entomobryidae). O. cincta uses a relatively simple cuticle structure with prima…

Direct electrochemical generation of organic carbonates by dehydrogenative coupling.

2018

Organic carbonates are an important source for polycarbonate synthesis. However, their synthesis generally requires phosgene, sophisticated catalysts, harsh reaction conditions, or other highly reactive chemicals. We present the first direct electrochemical generation of mesityl methyl carbonate by C–H activation. Although this reaction pathway is still challenging concerning scope and efficiency, it outlines a new strategy for carbonate generation.

Study regarding the physical-mechanical properties of knits for garments – pilling performance

2017

The effect of the pilling degradation results is an important decreasing in garment quality and a negative influence on the user’s comfort to wear. There are a lot factors, such as the yarn spinning system, fabric geometry and finishing operation, which affect the pilling performance. This research paper presents the investigation of fabric surface concerning pilling formation, especially knits, influenced by the fibrous composition. As samples were used knitted fabric panels, obtained from carded yarns, with fibers composition like cotton, wool or mixed one. Regarding fabric geometry 3 types were used – single jersey, 2x2 rib and moss stitch. In order to establish which of the yarns are mo…

Measuring the market power in the ceramic tile industry: An international comparison

2004

This paper measures the degree of competition faced by Spanish and Italian exporters of ceramic tiles in several European Union member states. The results indicate that Spanish producers have a substantial market power while Italian exporters face a high degree of competition. This finding is consistent with the significant gain (loss) in the world production and export shares that Spanish (Italian) producers experienced during the 1990s. The results are also consistent with accounting data. Furthermore, comparisons in the extent of market power across source countries and European destination markets reveal that most variation in the data is related to the source country. JEL no. F12, F14,…

1981

Dynamic-mechanical and dielectric measurements have been performed with some polycarbonate samples. In one set of experiments care was taken to avoid any absorption of moisture. In other sets of experiments, samples were exposed to atmospheric humidity and to boiling water. The glass transition temperature was found to be highly affected by the absorption of water and by the test conditions. Dynamisch-mechanische und dielektrische Messungen wurden an Polycarbonatproben durchgefuhrt. In einer Versuchsserie wurde die Absorption von Wasser vollstandig vermieden, in weitern Versuchen wurden die Proben der Luftfeuchte bzw. kochendem Wasser ausgesetzt. Die Glasubergangstemperatur wurde durch das …

Experimental Investigations and Numerical Analysis for Improving Knowledge of Incremental Sheet Forming Process for Sheet Metal Parts

2009

The paper is related to the analysis of shape distortions and springback effects arising in Single Point Incremental Forming. An experimental set up has been designed and manufactured to carry single point incremental forming on small size sheet metal parts. The experimental set up is mounted on 3-axes CNC milling machine tool and the forming tool is attached and move with the spindle. Experiments have been carried out on sheet metal parts to obtain tronconical shapes. The forming strategy associated to the movement of the forming tool has been also investigated. The experiments indicate that shape distortions arising in the corners of the tronconical shape are clearly related to forming st…

Helical Shift Mechanics of Rubber V-Belt Variators

2011

A very common configuration of V-belt variators for motorcycles considers the correction of the belt tensioning depending on the resistant torque by means of suitable helical-shaped tracks allowing the driven half-pulleys to close/open. The theoretical model for belt-pulley coupling is rather complex for this configuration, where one half-pulley may run in advance and the other one behind with respect to the belt, and requires the repeated numerical solution of a strongly nonlinear differential system by a sort of shooting technique, until all the operating conditions are fulfilled (angular contact extent, torque, and axial force). After solving the full equations, the present study develop…

Dynamic Stabilization of the Ligand-Metal Interface in Atomically Precise Gold Nanoclusters Au68 and Au144 Protected by meta-Mercaptobenzoic Acid

2017

Ligand-stabilized, atomically precise gold nanoclusters with a metal core of a uniform size of just 1–3 nm constitute an interesting class of nanomaterials with versatile possibilities for applications due to their size-dependent properties and modifiable ligand layers. The key to extending the usability of the clusters in applications is to understand the chemical bonding in the ligand layer as a function of cluster size and ligand structure. Previously, it has been shown that monodispersed gold nanoclusters, stabilized by meta-mercaptobenzoic acid (m-MBA or 3-MBA) ligands and with sizes of 68–144 gold atoms, show ambient stability. Here we show that a combination of nuclear magnetic reson…

Effect of Pre-Reduction on the Properties and the Catalytic Activity of Pd/Carbon Catalysts: A Comparison with Pd/Al2O3

2013

The effect of pre-reduction in solution with chemical reagents on the catalytic performance and catalyst properties of Pd/carbon catalysts was systematically investigated with a multitechnique approach. The results are critically discussed in comparison to those recently obtained on analogous Pd/alumina catalysts. It was proved that the Pd phase on the carbon surface is characterized by a high mobility, opposite to what occurs on alumina. As a result, the Pd particles on carbon aggregate together during pre-reduction, with a consequent decrease in available metal surface. Pd particles remain aggregated also in reaction conditions; the decreased Pd dispersion negatively affects the catalyst …