Search results for "visual_art"
showing 10 items of 2987 documents
The azido ligand: a useful tool in designing chain compounds exhibiting alternating ferro- and antiferro-magnetic interactions
1997
A one-pot reaction of NiII 1, CoII 2, FeII 3 and MnII 4 with 2,2A-bipyridine (bipy) and azide in water leads to [M(bipy)(N3)2]n chains where the metal ion is alternatively bridged by double end-on (EO) and end-to-end (EE) azido bridges; theoretical analysis of the variable-temperature magnetic susceptibility data of 1 and 4 reveals the occurrence of intrachain alternating ferro- (through EO) and antiferro-magnetic (through EE) interactions. Julve Olcina, Miguel, Miguel.Julve@uv.es ; Lloret Pastor, Francisco, Francisco.Lloret@uv.es ; Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es
Effect of filler on the creep characteristics of epoxy and epoxy-based CFRPs containing multi-walled carbon nanotubes
2014
The aim of this work was to determine the effect of carbon nanotubes (CNTs) on the elastic and viscoelastic properties of an epoxy resin used in carbon fiber-reinforced plastics (CFRPs) in the matrix-dominated flexural testing mode. Neat and CNTs-containing (1. wt.%) epoxy resin and CFRP specimens were prepared and investigated. Three-point bending tests were carried out on nanocomposite (NC) and CFRP specimens at room temperature in quasi-static and cyclic creep regimes. The main effect of CNTs was observed in the reduction of creep compliance of epoxy (40%) and CFRP (30%), especially at higher stresses. The reduction of creep characteristics especially on viscoelastic and plastic strains …
Spontaneous growth of 2D coordination polymers on functionalized ferromagnetic surfaces
2018
2D coordination polymers grow spontaneously on reactive surfaces due to surface oxidation. The growth process is observed in real time.
Multi-doped Brookite-Prevalent TiO2 Photocatalyst with Enhanced Activity in the Visible Light
2018
© 2018 Springer Science+Business Media, LLC, part of Springer Nature Abstract: Enabling solar and/or visible light-driven photocatalysis is a crucial step to access innovative applications in environmental science and sustainable energy. Titanium dioxide is the most used photocatalyst because of its low cost and toxicity, however it is also limitedly active under visible light irradiation due to its wide band gap. Among its polymorphs, brookite holds promising optoelectronic properties for visible light photocatalysis, which have to the best of our knowledge been limitedly exploited. Here, a C,S,N-doped brookite-based TiO2has been prepared via a rapid one-pot sol–gel synthesis. Besides subs…
A semiempirical correlation between the optical band gap of hydroxides and the electronegativity of their constituents
2000
In analogy with previous results on anhydrous oxides, a correlation is proposed between the optical band gap of hydroxides and the electronegativities of their constituents. Based on the experimental results on passive hydrated layers on metals obtained in our laboratory and the literature data, it is found that the hydroxide band gap varies with the square of the difference between the electronegativities of the metallic cation and the hydroxyl group. Like in the case of anhydrous oxides, two different interpolation lines have been found forsp-metal andd-metal hydroxides, respectively. The proposed correlations predict semiconducting or insulating behavior even for the most electronegative…
Effects of forest restoration treatments on the abundance of bark beetles in Norway spruce forests of southern Finland
2009
Abstract Restoration of protected areas in boreal forests frequently includes creating substantial volumes of dead wood. While this benefits a wide range of dead wood dependent invertebrate species, some of these are regarded as forest pests. Therefore, the risk of elevated levels of tree mortality in surrounding commercial forests must be considered. In a large-scale field experiment in southern Finland, we studied the effects of restoration treatments on the abundance of bark beetles within and in the vicinity of restored areas, in particular focusing on Ips typographus and Pityogenes chalcographus . The treatments applied to managed Norway spruce forests were controlled burning and parti…
Fe Mossbauer spectroscopy as a tool in astrobiology
2006
The element Fe and Fe-bearing minerals occur ubiquitously throughout the field of astrobiology. Cycling between the various oxidation states of Fe provides a source of energy available for life. Banded iron formations may record the rise of oxygenic photosynthesis. The distribution of Fe between Fe-bearing minerals and its oxidation states can help to characterize and understand ancient environments with respect to the suitability for life by constraining the primary rock type and the redox conditions under which it crystallized, the extent of alteration and weathering, the type of alteration and weathering products, and the processes and environmental conditions for alteration and weatheri…
Trace elements in natural metallic iron from Disko Island, Greenland
1986
The largest occurrence of natural metallic iron on Earth is on the island of Disko, Greenland. Metallic iron is found there in a variety of different types, from small metal particles in basalts to large meter-sized blocks. We have studied three different types of metallic iron: small metal spherules (< 300 μm) in basaltic magma; larger metal grains (300 μm-3 mm), often composed of aggregates of smaller particles, in similar host rocks; and massive iron lumps (up to several tons). Analytical data for 13 siderophile elements in samples from these three types are presented. All metals analysed have a distinctly crustal pattern of siderophile elements. High Co/Ni, Re/Ir or W/Ir ratios clearly …
Glass-basalt/epoxy hybrid composites for marine applications
2011
Abstract The aim of this work is to evaluate the influence of uniaxial basalt fabric layers on the mechanical performances of a glass mat/epoxy composite used for marine applications. Polymer composites, reinforced by glass mat (GFRP), and hybrid ones, reinforced by glass mat and unidirectional basalt fabric, have been produced by vacuum bagging technique. Three points bending and tensile tests have been carried out in order to evaluate the effect of number and position of basalt layers on the mechanical properties of the investigated structures. The experimental tests have showed that the presence of two external layers of basalt involves the highest increase in mechanical properties of hy…
Chemical composition of modern and fossil hippopotamid teeth and implications for paleoenvironmental reconstructions and enamel formation – Part 2: A…
2012
Abstract. For reconstructing environmental change in terrestrial realms the geochemistry of fossil bioapatite in bones and teeth is among the most promising applications. This study demonstrates that alkaline earth elements in enamel of Hippopotamids, in particular Ba and Sr are tracers for water provenance and hydrochemistry. The studied specimens are molar teeth from Hippopotamids found in modern and fossil lacustrine settings of the Western Branch of the East African Rift system (Lake Kikorongo, Lake Albert, and Lake Malawi) and from modern fluvial environments of the Nile River. Concentrations in enamel vary by ca. two orders of magnitude for Ba (120–9336 μg g−1) as well as for Sr (9–21…