Search results for "water vapor"
showing 10 items of 179 documents
Comments on surface structure analysis by water and nitrogen adsorption
2004
Specific surface area and pore size distribution are determined usually from adsorption isotherms at low temperatures using nitrogen or noble gases. These are not absolute parameters and the measuring methods are fraught with serious difficulties. General problems of sorption measurements and recent developments are discussed. To obtain information for practical purposes these measurements need to be supplemented by investigations of the sorbate/sorbent system used in practice. Results of the measurement of nitrogen and water vapour adsorption on different materials are compared.
Challenges in the atmospheric characterization for the retrieval of spectrally resolved fluorescence and PRI region dynamics from space
2021
Abstract In the coming years, Earth Observation missions like the FLuorescence EXplorer (FLEX) will acquire the radiance signal from the visible to the near-infrared at a very high spectral resolution, enabling exciting prospects for new insights in satellite-based photosynthetic studies. In this context, the process of de-coupling atmospheric and vegetation-related spectral signatures will become essential to guarantee a reliable estimation of the vegetation photosynthetic activity from space. Dynamic changes related to the vegetation photosynthetic status result in subtle contributions to the top of atmosphere radiance signal, e.g. due to the emission of the solar-induced chlorophyll fluo…
Cloud detection for CHRIS/Proba hyperspectral images
2005
Accurate and automatic detection of clouds in satellite scenes is a key issue for a wide range of remote sensing applications. With no accurate cloud masking, undetected clouds are one of the most significant source of error in both sea and land cover biophysical parameter retrieval. Sensors with spectral channels beyond 1 um have demonstrated good capabilities to perform cloud masking. This spectral range can not be exploited by recently developed hyperspectral sensors that work in the spectral range between 400- 1000 nm. However, one can take advantage of their high number of channels and spectral resolution to increase the cloud detection accuracy, and to describe properly the detected c…
Coupled retrieval of aerosol optical thickness, columnar water vapor and surface reflectance maps from ENVISAT/MERIS data over land
2008
An algorithm for the derivation of atmospheric parameters and surface reflectance data from MEdium Resolution Imaging Specrometer Instrument (MERIS) on board ENVIronmental SATellite (ENVISAT) images has been developed. Geo-rectified aerosol optical thickness (AOT), columnar water vapor (CWV) and spectral surface reflectance maps are generated from MERIS Level-1b data over land. The algorithm has been implemented so that AOT, CWV and reflectance products are provided on an operational manner, making no use of ancillary parameters apart from those attached to MERIS products. For this reason, it has been named Self-Contained Atmospheric Parameters Estimation from MERIS data (SCAPE-M). The fund…
Rapid chemical evolution of tropospheric volcanic emissions from Redoubt Volcano, Alaska, based on observations of ozone and halogen-containing gases
2013
Abstract We report results from an observational and modeling study of reactive chemistry in the tropospheric plume emitted by Redoubt Volcano, Alaska. Our measurements include the first observations of Br and I degassing from an Alaskan volcano, the first study of O 3 evolution in a volcanic plume, as well as the first detection of BrO in the plume of a passively degassing Alaskan volcano. This study also represents the first detailed spatially-resolved comparison of measured and modeled O 3 depletion in a volcanic plume. The composition of the plume was measured on June 20, 2010 using base-treated filter packs (for F, Cl, Br, I, and S) at the crater rim and by an instrumented fixed-wing a…
Susceptibility of contrail ice crystal numbers to aircraft soot particle emissions
2017
We develop an idealized, physically-based model describing combined effects of ice nucleation and sublimation on ice crystal number during persistent contrail formation. Our study represents the first effort to predict ice numbers at the point where contrails transition into contrail cirrus—several minutes past formation—by connecting them to aircraft soot particle emissions and atmospheric supersaturation with respect to ice. Results averaged over an observed exponential distribution of ice supersaturation (mean value 15%) indicate that large reductions in soot particle numbers are needed to lower contrail ice crystal numbers significantly for soot emission indices around 1015 (kg-fuel)−1,…
Structure and Dynamics of the Instantaneous Water/Vapor Interface Revisited by Path-Integral and Ab Initio Molecular Dynamics Simulations
2015
The structure and dynamics of the water/vapor interface is revisited by means of path-integral and second-generation Car-Parrinello ab-initio molecular dynamics simulations in conjunction with an instantaneous surface definition [A. P. Willard and D. Chandler, J. Phys. Chem. B 114, 1954 (2010)]. In agreement with previous studies, we find that one of the OH bonds of the water molecules in the topmost layer is pointing out of the water into the vapor phase, while the orientation of the underlying layer is reversed. Therebetween, an additional water layer is detected, where the molecules are aligned parallel to the instantaneous water surface.
Surface temperature and water vapour retrieval from MODIS data
2003
This paper gives operational algorithms for retrieving sea (SST), land surface temperature (LST) and total atmospheric water vapour content (W) using Moderate Resolution Imaging Spectroradiometer (MODIS) data. To this end, the MODTRAN 3.5 radiative transfer program was used to predict radiances for MODIS channels 31, 32, 2, 17, 18 and 19. To analyse atmospheric effects, a simulation with a set of radiosonde observations was used to cover the variability of surface temperature and water vapour concentration on a worldwide scale. These simulated data were split into two sets (DB1 and DB2), the first one (DB1) was used to fit the coefficients of the algorithms, while the second one (DB2) was u…
Retrieval of characteristic parameters for water vapour transmittance in the development of ground based Sun-Sky radiometric measurements of columnar…
2014
Abstract. Sun–sky radiometers are instruments created for aerosol study, but they can measure in the water vapour absorption band allowing the estimation of columnar water vapour in clear sky simultaneously with aerosol characteristics, with high temporal resolution. A new methodology is presented for estimating calibration parameters (i.e. characteristic parameters of the atmospheric transmittance and solar calibration constant) directly from the sun–sky radiometer measurements. The methodology is based on the hypothesis that characteristic parameters of the atmospheric transmittance are dependent on vertical profiles of pressure, temperature and moisture occurring at each site of measurem…
Precipitable water vapour content from ESR/SKYNET sun-sky radiometers: validation against GNSS/GPS and AERONET over three different sites in Europe
2018
The estimation of the precipitable water vapour content (W) with high temporal and spatial resolution is of great interest to both meteorological and climatological studies. Several methodologies based on remote sensing techniques have been recently developed in order to obtain accurate and frequent measurements of this atmospheric parameter. Among them, the relative low cost and easy deployment of sun–sky radiometers, or sun photometers, operating in several international networks, allowed the development of automatic estimations of W from these instruments with high temporal resolution. However, the great problem of this methodology is the estimation of the sun-photometric calibration par…