Search results for "yield"
showing 10 items of 1338 documents
On the order of the herringbone transition of N2 on graphite: a Monte Carlo study
1993
Using the anisotropic planar-rotor model we investigate the herringbone phase transition of N2 in the (√3 × √3)R30° commensurate phase on graphite by large scale Monte Carlo simulations. The effective correlation length ξ is measured near the transition temperature T0. The data, extrapolated to T0, yield a large but finite ξ at T0 demonstrating that the herringb ordering is a weak first order transition.
Efficient orange light-emitting electrochemical cells
2012
We report the first bis-cyclometalated cationic iridium(III) complex with N-aryl-substituted 1H-imidazo [4,5-f][1,10]phenanthroline. The complex emits yellow-orange phosphorescence with a maximum at 583 nm, a quantum yield of 43%, and an excited-state lifetime of 910 ns in argon-saturated dichloromethane. Optimized orange light-emitting electrochemical cells with the new Ir(III) complex exhibit fast turn-on, a peak luminance of 684 cd m(-2) and a peak efficacy of 6.5 cd A(-1); in 850 h of continuous operation their luminance and efficacy decrease only by 20%.
Bio-agronomic behaviour and an initial study of the energy properties of Carthamus tinctorius L. and Brassica carinata A. Braun crop residues
2009
In recent years, the agro-energy sector has become of considerable importance, both as a vehicle towards realising the objectives established by the Kyoto protocol and as a means of meeting the ever increasing demand for energy. Biofuels represent one of the most promising forms of renewable energy due to their wide range of applications, although limited by the fact that they do not compete on a cost level with fossil fuels. This study takes a look at the bio-agronomic response and the physical and energetic properties of crop residues of a selection of Carthamus tinctorius L. and Brassica carinata A. Braun accessions in order to evaluate integrating oilseed production with lignocellulosic…
Preparation of Carbon-14 Labeled 2-(2-mercaptoacetamido)-3-phenylpropanoic Acid as Metallo-beta-lactamases Inhibitor (MBLI), for Coadministration wit…
2019
Aim and Objective: Bacteria could become resistant to β-lactam antibiotics through production of β- lactamase enzymes like metallo-β-lactamase. 2-(2-mercaptoacetamido)-3-phenylpropanoic acid was reported as a model inhibitor for this enzyme. In order to elucidate the mechanism of action in the body’s internal environment, preparation of a labeled version of 2-(2-mercaptoacetamido)-3-phenylpropanoic acid finds importance. In this regard, we report a convenient synthetic pathway for preparation of carbon-14 labeled 2-(2- mercaptoacetamido)-3-phenylpropanoic acid. Materials and Methods: This study was initiated by using non-radioactive materials. Then, necessary characterization was performed…
PHOSPHOROUS SEED COATING AFFECT TO GERMINATION, PHOTOSYNTHETIC PIGMENTS AND YIELD OF RAPE
2005
Rape (Brassica napus L. var. napus) is long ago-known vegetable of Brassicaceae in agriculture. It is important and valuable oil, forage, green-fertiliser and nectar plant. The experience of last years shows that rape is suitable for growing in conditions of Latvia, but investigations about its cultivars and growing technologies are not wide enough.The phosporus-fertilizer adding in the rape plantations is of great importance for increasing of its productivity. With the aim to reduce the expenses the phosphorus treated rape seeds are made use.In our investigations the velocity of seeds germination, germinating viability, germinating vigour, green pigments” quantity in seed-lobes and seeds” …
Special needs and characteristic features of (photo)catalytic reactors with a review of the proposed Solutions
2019
Abstract In the present chapter, the analogies between photocatalytic systems and the systems where the more common thermally activated reactions take place are highlighted. The objective is to propose a unified approach for the analysis and the design, which, however, must take into account how and why photocatalytic reactors differ from reactors with thermal reactions. The necessity of absorbing photons to activate the photocatalytic process adds complexity to the system, but some approaches are presented to simplify the problems and make easier their solution.
Subsurface treatment of a contact subjected to a hertz pressure
2013
Abstract The study proposes an approach allowing the favorable modification of the stresses field of a structure subjected to a Hertzian contact. It is based on the study of a classic Hertzian contact in the presence of subsurface circular defects. The idea is to limit the field of tangential stresses without large increasing of the global stress (Von Mises) of the system. The location of the defects is made according to the mechanical parameters of the contact (Fn, has, z). The results of the numerical calculations (FEM) are compared with photoelastic measurements and highlight an excellent correlation. The location of the defect on the symmetry axis (x=0) is the dominating parameter for t…
Changes of the Quantum Yield of Oxygen Evolution and the Electron Transport Capacity of Isolated Spinach Thylakoids during Photoinhibition
1992
Summary Isolated spinach thylakoids can be protected from photoinhibitory loss of electron transport capacity by the radical defense system composed of the enzymes SOD and catalase, as well as the antioxidants glutathione and ascorbate. With these compounds present at saturating concentrations, thylakoids not only retain a high photochemical capacity but also do not suffer D1-protein degradation during photoinhibition. However, a strong decrease in the quantum yield of oxygen evolution, Φ O 2 , occurs with the same thylakoids. These results support the view that the photochemical capacity and the quantum yield of oxygen evolution decline due to different mechanisms during photoinhibition. T…
Pyrene-benzoylthiophene Bichromophores as Selective Triplet Photosensitizers.
2006
Combination of the pyrene and benzoylthiophene units constitutes an interesting approach to design bichromophoric photosensitizers with increased intersystem crossing quantum yield and enhanced selectivity. The potential of this strategy has been illustrated in the present work by using a model photoisomerization reaction.
Carborane-stilbene dyads: influence of substituents and cluster isomers on the photoluminescence properties
2017
Two novel styrene-containing meta-carborane derivatives substituted at the second carbon cluster atom (Cc) with either a methyl (Me), or a phenyl (Ph) group, are introduced herein alongside with a new set of stilbene-containing ortho- (o-) and meta- (m-) carborane dyads. The latter set of compounds has been prepared from styrenecontaining carborane derivatives via Heck coupling reaction. High regioselectivity has been achieved for these compounds by using a combination of palladium complexes [Pd2(dba)3]/[Pd(t-Bu3P)2] as a catalytic system, yielding exclusively E isomers. All compounds have been fully characterized and the crystal structures of seven of them analyzed by X-ray diffraction. Th…