Search results for "zircon"
showing 10 items of 693 documents
Effect of AlR3 (R = Me, Et, iBu) addition on the composition and microstructure of ethylene/1-olefin copolymers made with post-metallocene complexes …
2018
The effect of trialkylaluminum compound (AlR3, where R = Me, Et, iBu) addition on the performance of the [LigZrCl]2(μ-O)/AliBu3/Ph3CB(C6F5)4 and LigTiCl2/AliBu3/Ph3CB(C6F5)4 (Lig = Me2N(CH2)2N(CH2-2-O-3,5-tBu2-C6H2)2) catalysts in ethylene/1-olefin copolymerization was investigated. The presence of AlMe3 in the feed during the copolymerization process catalyzed by the diamine-bis(phenolate) zirconium catalyst greatly increases the amount of incorporated comonomer and leads to microstructural changes, e.g., the formation of blocky and alternating sequences of 1-olefin units. Moreover, the use of AlMe3 limits the reaction yield and decreases the molecular weight of the produced copolymers. Th…
Non‐subduction origin for 3.2 Ga high‐pressure metamorphic rocks in the Barberton granitoid‐greenstone terrane, South Africa
2019
The occurrence of high-pressure (HP) garnet-bearing metamorphic rocks in the southern Barberton granitoid-greenstone terrane (BGGT), South Africa, has been proposed as a key indicator of the onset of modern plate tectonics at ca. 3.2 Ga. Here, we report new zircon/titanite U-Pb ages of garnet-bearing HP metamorphic rocks and associated granitoids in the BGGT that argue against such an interpretation. The results show that HP metamorphism occurred synchronously with granitoid magmatism in the Stolzburg domain, the supposed subducted plate, during two episodes at 3.4 and 3.2 Ga, and that these two episodes of magmatism occurred on both sides of the assumed suture zone, a feature that cannot e…
Effects of natural radiation damage on back-scattered electron images of single crystals of minerals
2006
Generally, it has been assumed that signal intensity variations in back-scattered electron (BSE) images of minerals are mainly controlled by chemical heterogeneity. This is especially true for images of single crystals, where effects of different crystal orientations with respect to the incident beam on the observed BSE are excluded. In contrast, we show that local variations of the structural state within single-crystals (i.e., degree of lattice order or lattice imperfectness) may also have dramatic effects on the back-scattering of electrons. As an example, we present BSE images of single-crystals of natural zircon, ZrSiO 4 , whose intensity patterns are predominantly controlled by struct…
Multiple intrusive phases in the Leinster Batholith, Ireland: geochronology, isotope geochemistry and constraints on the deformation history
2017
The formation of granite batholiths, commonly by incremental assembly of small magma batches, and their correlation with tectonic events, on both local and regional scales, is crucial to understanding the evolution of the Earth9s continental crust. However, these correlations often rely on assumptions about the detailed relationship and timing of mapped units. Here we report how an integrated geochronological, structural and isotope geochemical study in only one key locality from the late Caledonian Leinster Batholith in SE Ireland provides the potential for unravelling essential questions on batholith petrogenesis. The Northern Unit of the Leinster Batholith intruded incrementally, as demo…
Zircon and muscovite ages, geochemistry, and Nd-Hf isotopes for the Aktyuz metamorphic terrane: Evidence for an Early Ordovician collisional belt in …
2011
International audience; The Aktyuz metamorphic terrane in the Kyrgyz northern Tianshan consists of granitoid gneisses and migmatites with subordinate paragneisses, greenschists, presumed meta-ophiolites, and garnet amphibolite dykes that contain HP eclogite relicts. The gneisses and migmatites were previously considered to be Archaean and Palaeoproterozoic in age on the basis of α-Pb and U-Pb multigrain zircon dating. Zircons from a post-tectonic granite were previously dated at 692 ± 15 Ma, constraining the time of main deformation and metamorphism in the Aktyuz terrane to the Precambrian. The chemical characteristics of most granitoid samples are consistent with melting of chemically evol…
The behaviour of zirconium, hafnium and rare earth elements during the crystallisation of halite and other salt minerals
2017
Abstract Halite crystals from Messinian and Tortonian evaporites from Sicily and Spain and current precipitated halite crystals and the relative parent brines (active evaporation systems) were investigated in order to evaluate the Zr, Hf and Rare Earth Element (REE) behaviour. Halite crystallisation from evaporating brines fractionates Zr, Hf and REE through a two-step process. During the first step, dissolved complexes of studied elements are scavenged onto the surfaces of crystallising halite. During the second step, elements are co-precipitated into the crystal lattice as it grows. The first step mechanism is determined by the dissolved REE speciation. In saltworks where carbonate-REE co…
Igneous petrology, zircon geochronology and geochemistry of multiply emplaced granitoid bodies from the Palaeoproterozoic Usagaran domain in central …
2019
Abstract This study reports igneous petrology, zircon ages and geochemistry for Palaeoproterozoic I-type granitic, granodioritic, Qtz-monzonitic, Qtz-monzodioritic and monzodioritic rocks from the Usagaran domain of southwestern Tanzania. These rocks can be subdivided into three groups according to their age, T-t evolution and geochemistry. The oldest group is made up of amphibolite-facies calcic-alkalic gneisses, ranging in age between ∼1984 and ∼1910 Ma, which have been divided into two subgroups regarding their T-t evolution. The first subgroup shows a constant increase in T, and the second subgroup first shows a decrease in T, followed by an increase in T. The second group consists of a…
Late Palaeoproterozoic depositional age for khondalite protoliths in southern India and tectonic implications
2016
Abstract SHRIMP dating of detrital zircons from garnet–sillimanite–cordierite paragneisses (khondalites) of the Trivandrum Block, southern India, revealed nanometer-scale Pb isotopic inhomogeneity in most grains that we ascribe to annealing processes during ultra-high-temperature metamorphism at ca. 570 Ma. Our age data for zircons from six representative khondalite samples do not document any Neo- or Mesoproterozoic detrital grains, and we conclude from the concordant ages and discordant minimum 207Pb/206Pb ages that the khondalite precursor sediments were deposited more than 2.1 Ga ago and were subsequently intruded by granitoid rocks at ca. 1765–2100 Ma. Some detrital zircons in the khon…
Phase Relations, Reaction Sequences and Petrochronology
2017
At the core of petrochronology is the relationship between geochronology and the petrological evolution of major mineral assemblages. The focus of this chapter is on outlining some of the available strategies to link inferred reaction sequences and microstructures in metamorphic rocks to the ages obtained from geochronology of accessory minerals and datable major minerals. Reaction sequences and mineral assemblages in metamorphic rocks are primarily a function of pressure ( P ), temperature ( T ) and bulk composition ( X ). Several of the major rock-forming minerals are particularly sensitive to changes in P–T (e.g., garnet, staurolite, biotite, plagioclase), but their direct geochronology …
Long-term stability of alpha particle damage in natural zircon
2005
Abstract We report the first discovery of radiation damage haloes generated by alpha particles in zircon. Proterozoic zircon crystals from a potassium-rich leucogranite from the Adirondack Mountains, New York State, have interior regions that are generally low in actinide elements (UO 2 + ThO 2 ≤ 0.02 wt.%) but show a remarkable pattern of heterogeneous metamictisation. The degree of radiation damage in these regions is not uniformly low, as would be expected if it corresponded to the observed actinide distribution patterns and age of the crystals. Rather, radiation damage is significantly increased in the outermost micro-areas of the low-actinide regions. The additional radiation damage …