0000000000004116
AUTHOR
R. Murugesan
catena-Poly[[(18-crown-6-κ6O)potassium]-μ-chlorido-[(1H-benzotriazol-1-ol-κN3)chloridoplatinum(II)]-μ-(benzotriazol-1-olato-κ2N3:O)]
In the structure of the title compound, [KPt(C6H4N3O)Cl2(C6H5N3O)(C12H24O6)], the PtII atom is in a distorted square-planar geometry. The crystal structure is consolidated by O—H⋯O hydrogen bonds. The measured crystal was a non-merohedral twin with four components.
Tetra-μ-chlorido-bis(18-crown-6)platinum(II)dipotassium(I)
In the title compound, [K(2)PtCl(4)(C(12)H(24)O(6))(2)], the Pt(II) ion is located on an inversion centre and is coordinated by four Cl atoms, forming a square-planar geometry. The K(I) ion is coordinated by six O atoms of the crown ether and two bridging Cl atoms. The K(I) ion is displaced by 0.756 (2) Å from the mean plane of the six O atoms of the crown ether. The mol-ecules are connected by weak C-H⋯O hydrogen bonds, forming an infinite two-dimensional network parallel to the (10) plane. Intra- and inter-molecular C-H⋯Cl hydrogen bonds are also observed.
1-Mesitylmethyl-1Hbenzotriazole 3-oxide.
In the title compound, C16H17N3O, the benzotriazole ring forms a dihedral angle of 77.25 (6)° with the phenyl ring. The benzotriazole ring is essentially planar with a maximum deviation of 0.012 (19) Å. Weak intermolecular C—H...O hydrogen bonds form R22(10) motifs. The crystal packing is consolidated by π—π interactions with centroid–centroid distances of 3.5994 (12) Å together with very weak C—H...π interactions.
catena-Poly[[aquasodium(I)]-μ-[2,2′-(disulfanediyl)bis(pyridineN-oxide)]-μ-(pyridine-2-thiolato 1-oxide)]
There are two monomeric units in the asymmetric unit of the polymeric title compound, [Na(C(5)H(4)NOS)(C(10)H(8)N(2)O(2)S(2))(H(2)O)](n). The Na(I) ions are six coordinated by four O atoms, one S atom and one water mol-ecule, forming a slightly distorted octa-hedral geometry. An intra-molecular O-H⋯O hydrogen bond stabilizes the conformation of the mol-ecule. The crystal packing is consolidated by inter-molecular O-H⋯O, O-H⋯N and O-H⋯S hydrogen bonds, π-π inter-actions [with centroid-centroid distances of 3.587 (2) Å] together with weak C-H⋯π inter-actions. The mol-ecules are linked into polymeric chains along the b-axis direction.
CCDC 720015: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, J.Shakina, R.Murugesan, D.Schollmeyr|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|m631|doi:10.1107/S1600536810015898
CCDC 730605: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, J.Devadasan, R.Murugesan, D.Schollmeyer|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|m142|doi:10.1107/S1600536810000073
CCDC 770024: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, J.Shakina, R.Murugesan, D.Schollmeyer|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|o637|doi:10.1107/S1600536810004824
CCDC 781217: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, D.Kalavathy, R.Murugesan, D.Schollmeyer|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|m667|doi:10.1107/S1600536810016648