6533b7dcfe1ef96bd1272bcd
RESEARCH PRODUCT
Tetra-μ-chlorido-bis(18-crown-6)platinum(II)dipotassium(I)
Dieter SchollmeyerB. Ravindran Durai NayagamR. MurugesanSamuel Robinson JebasD. Kalavathysubject
Metal-Organic Paperschemistry.chemical_classificationbiologyHydrogen bond18-Crown-6chemistry.chemical_elementGeneral ChemistryCondensed Matter Physicsbiology.organism_classificationBioinformaticsIonchemistry.chemical_compoundCrystallographychemistryTetraGeneral Materials SciencePlatinumCrown etherdescription
In the title compound, [K(2)PtCl(4)(C(12)H(24)O(6))(2)], the Pt(II) ion is located on an inversion centre and is coordinated by four Cl atoms, forming a square-planar geometry. The K(I) ion is coordinated by six O atoms of the crown ether and two bridging Cl atoms. The K(I) ion is displaced by 0.756 (2) Å from the mean plane of the six O atoms of the crown ether. The mol-ecules are connected by weak C-H⋯O hydrogen bonds, forming an infinite two-dimensional network parallel to the (10) plane. Intra- and inter-molecular C-H⋯Cl hydrogen bonds are also observed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-05-01 | Acta Crystallographica Section E Structure Reports Online |