0000000000006016
AUTHOR
E.b. Mkadmi
Study of the Fundamental Bands of 70GeD4 by High-Resolution Raman and Infrared Spectroscopy: First Experimental Determination of the Equilibrium Bond Length of Germane
Abstract The four fundamental bands of 70 GeD 4 have been analyzed using the STDS software developed in Dijon (http://www.u-bourgogne.fr/LPUB/sTDS.html). Both infrared and Raman spectra were used to observe all fundamental bands. Infrared spectra of monoisotopic 70 GeD 4 were recorded in the regions 600 and 1500 cm −1 using the Bruker 120HR interferometer at Wuppertal. The resolution (1/maximum optical path difference) was between 2.3 and 3.3×10 −3 cm −1 for the ν 3 and ν 4 infrared-active fundamental bands as well as for the interacting ν 2 band. A high-resolution stimulated Raman spectrum of the ν 1 band has been recorded in Madrid. The instrumental resolution of the Raman spectrum was 3.…
High-Resolution Spectroscopy and Analysis of the ν3 and ν4 Fundamentals of Monoisotopic 70GeF4
The first high-resolution study on germanium tetrafluoride is reported. We used a monoisotopic sample of (70)GeF(4). The FTIR spectra of the two infrared active fundamentals, namely the nu(4) (bending) and nu(3) (stretching) modes, were recorded at a temperature of ca. 210 K and a resolution (1/maximum optical path difference) of 0.0031 and 0.0023 cm(-1), respectively. These spectra were analyzed using the STDS software developed in Dijon. In both cases, we obtained a fit with a root mean square better than 1x10(-3) cm(-1). Both bands show very regular structures with no detectable perturbation. Copyright 2001 Academic Press.
High-resolution Fourier transform infrared spectroscopy and analysis of the ν3 fundamental band of P4
Abstract We present the first high-resolution infrared absorption study of the ν 3 fundamental of white phosphorus, P 4 . This spectrum has been analyzed using the STDS (Spherical Top Data System) software. The band center lies at 466.286 cm −1 . With the approximation ( Bζ ) 3 =− B 0 /2, we found that the ground-state bond length is r 0 =219.58 pm. This value is consistent with that of ab initio studies reported previously but significantly different from a value obtained from a Raman study.