0000000000011907

AUTHOR

Javier Conesa-egea

Electrical conductivity and strong luminescence in copper Iodide double chains with isonicotinato derivatives

Direct reactions between CuI and isonicotinic acid (HIN) or the corresponding esters, ethyl isonicotinate (EtIN) or methyl isonicotinate (MeIN), give rise to the formation of the coordination polymers [CuI(L)] with L=EtIN (1), MeIN (2) and HIN (3). Polymers 1-3 show similar structures based on a CuI double chain in which ethyl-, methyl isonicotinate or isonicotinic acid are coordinated as terminal ligands. Albeit, their supramolecular architecture differs considerably, affecting the distances and angles of the central CuI double chains and thereby their physical properties. Hence, the photoluminescence shows remarkable differences; 1 and 2 show a strong yellow emission, whereas 3 displays a…

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Smart composite films of nanometric thickness based on copper-iodine coordination polymers. Toward sensors.

One-pot reactions between CuI and methyl or methyl 2-amino-isonicotinate give rise to the formation of two coordination polymers (CPs) based on double zig-zag Cu2I2 chains. The presence of a NH2 group in the isonicotinate ligand produces different supramolecular interactions affecting the Cu-Cu distances and symmetry of the Cu2I2 chains. These structural variations significantly modulate their physical properties. Thus, both CPs are semiconductors and also show reversible thermo/mechanoluminescence. X-ray diffraction studies carried out under different temperature and pressure conditions in combination with theoretical calculations have been used to rationalize the multi-stimuli-responsive …

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Control and Simplicity in the Nanoprocessing of Semiconducting Copper-Iodine Double Chain Coordination Polymers

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.8b00364

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Back Cover: Electrical Conductivity and Strong Luminescence in Copper Iodide Double Chains with Isonicotinato Derivatives (Chem. Eur. J. 48/2015)

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CCDC 1826854: Experimental Crystal Structure Determination

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CCDC 1865233: Experimental Crystal Structure Determination

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CCDC 1826851: Experimental Crystal Structure Determination

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CCDC 1047310: Experimental Crystal Structure Determination

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CCDC 1826848: Experimental Crystal Structure Determination

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CCDC 1401258: Experimental Crystal Structure Determination

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CCDC 1826858: Experimental Crystal Structure Determination

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CCDC 1826857: Experimental Crystal Structure Determination

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CCDC 1826853: Experimental Crystal Structure Determination

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CCDC 1047311: Experimental Crystal Structure Determination

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CCDC 1403318: Experimental Crystal Structure Determination

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CCDC 1826849: Experimental Crystal Structure Determination

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CCDC 1826850: Experimental Crystal Structure Determination

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CCDC 1826847: Experimental Crystal Structure Determination

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CCDC 1047309: Experimental Crystal Structure Determination

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CCDC 1826855: Experimental Crystal Structure Determination

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CCDC 1580668: Experimental Crystal Structure Determination

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CCDC 1826852: Experimental Crystal Structure Determination

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CCDC 1826846: Experimental Crystal Structure Determination

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CCDC 1826856: Experimental Crystal Structure Determination

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