0000000000013568

AUTHOR

Changsheng Wang

showing 5 related works from this author

The Interplay of Inverted Redox Potentials and Aromaticity in the Oxidized States of New π-Electron Donors: 9-(1,3-Dithiol-2-ylidene)fluorene and 9-(…

2006

Derivatives of 9-(1,3-dithiol-2-ylidene)fluorene (9) and 9-(1,3-dithiol-2-ylidene)thioxanthene (10) have been synthesised using Horner-Wadsworth-Emmons reactions of (1,3-dithiol-2-yl)phosphonate reagents with fluorenone and thioxanthen-9-one. X-ray crystallography, solution electrochemistry, optical spectroscopy, spectroelectrochemistry and simultaneous electrochemistry and electron paramagnetic resonance (SEEPR), combined with theoretical calculations performed at the B3P86/6-31G** level, elucidate the interplay of the electronic and structural properties in these molecules. These compounds are strong two-electron donors, and the oxidation potentials depend on the electronic structure of t…

Organic ChemistryThioxantheneDithiolAromaticitySulfoxideGeneral ChemistryFluorenePhotochemistryCatalysisDicationchemistry.chemical_compoundchemistryFluorenoneRadical ionChemistry - A European Journal
researchProduct

CCDC 285999: Experimental Crystal Structure Determination

2006

Related Article: S.Amriou, Changsheng Wang, A.S.Batsanov, M.R.Bryce, D.F.Perepichka, E.Orti, R.Viruela, J.Vidal-Gancedo, C.Rovira|2006|Chem.-Eur.J.|12|3389|doi:10.1002/chem.200501326

Space GroupCrystallography27-bis(4-t-butylphenyl)-9-(45-dimethyl-13-dithiol-2-ylidene)fluorene deuterochloroform solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 286001: Experimental Crystal Structure Determination

2006

Related Article: S.Amriou, Changsheng Wang, A.S.Batsanov, M.R.Bryce, D.F.Perepichka, E.Orti, R.Viruela, J.Vidal-Gancedo, C.Rovira|2006|Chem.-Eur.J.|12|3389|doi:10.1002/chem.200501326

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters9-(45-dimethyl-13-dithiol-2-ylidene)thioxanthene SS-dioxide ethyl acetate solvateExperimental 3D Coordinates
researchProduct

CCDC 286000: Experimental Crystal Structure Determination

2006

Related Article: S.Amriou, Changsheng Wang, A.S.Batsanov, M.R.Bryce, D.F.Perepichka, E.Orti, R.Viruela, J.Vidal-Gancedo, C.Rovira|2006|Chem.-Eur.J.|12|3389|doi:10.1002/chem.200501326

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters9-(45-dimethyl-13-dithiol-2-ylidene)thioxantheneExperimental 3D Coordinates
researchProduct

CCDC 285998: Experimental Crystal Structure Determination

2006

Related Article: S.Amriou, Changsheng Wang, A.S.Batsanov, M.R.Bryce, D.F.Perepichka, E.Orti, R.Viruela, J.Vidal-Gancedo, C.Rovira|2006|Chem.-Eur.J.|12|3389|doi:10.1002/chem.200501326

27-di-iodo-9-(45-dimethyl-13-dithiol-2-ylidene)fluoreneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct