0000000000017947

AUTHOR

Arturo Gamonal

showing 2 related works from this author

Divergent Adsorption-Dependent Luminescence of Amino-Functionalized Lanthanide Metal-Organic Frameworks for Highly Sensitive NO2 Sensors

2020

International audience; A novel gas sensing mechanism exploiting lanthanide luminescence modulation upon NO2 adsorption is demonstrated here. Two isostructural lanthanide-based metal–organic frameworks (MOFs) are used, including an amino group as the sensitive recognition center for NO2 molecules. The transfer of energy from the organic ligands to Ln is strongly dependent on the presence of NO2, resulting in an unprecedented photoluminescent sensing scheme. Thereby, NO2 exposition triggers either a reversible enhancement or a decrease in the luminescence intensity, depending on the lanthanide ion (Eu or Tb). Our experimental studies combined with density functional theory and complete activ…

LanthanideIonsPhotoluminescenceLuminescenceChemistryLigandAb initioMetal organic frameworks02 engineering and technology[CHIM.MATE]Chemical Sciences/Material chemistryMolecules010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistryLigands01 natural sciences0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryAdsorptionGeneral Materials ScienceMetal-organic frameworkPhysical and Theoretical ChemistryIsostructural0210 nano-technologyLuminescence
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Sierra del Colmenar 1A, a new late Messinian (Late Miocene) locality in the Bajo Segura Basin (SE Spain): biostratigraphic and palaeoenvironmental im…

2017

In this paper, we have studied a new micromammal site from the Sierra del Colmenar section (Elche, SE Spain), named Sierra del Colmenar 1A (SCO-1A), representing the uppermost levels of Messinian age of the Bajo Segura Basin. The sedimentary context of this locality corresponds to a costal lagoon with marine influence. The fossil site has yielded remains of Apodemus aff. gorafensis, Paraethomys meini, Apocricetus alberti, Occitanomys alcalai, Ruscinomys sp., Eliomys cf. truci, Muscardinus sp., Parasorex ibericus, Prolagus michauxi and Soricidae indet. Based on this assemblage, we propose a Late Miocene age (MN13) for the locality SCO-1A, matching the previously inferred age for the stratigr…

010506 paleontologyBajo Segura BasinEstratigrafíaRodentiaParaethomysLate MioceneStructural basin010502 geochemistry & geophysics01 natural sciencesPaleontologyMessinianSection (archaeology)TurolianGeneral Agricultural and Biological SciencesGeology0105 earth and related environmental sciencesHistorical Biology
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