0000000000020520

AUTHOR

Miguel Palomino

showing 21 related works from this author

A highly stable and hierarchical tetrathiafulvalene-based metal organic framework with improved performance as a solid catalyst

2018

[EN] Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(¿3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

Solucions polimèriquesMaterials scienceQuímica organometàl·licaCrystal structure010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundQUIMICA ORGANICAMOFAqueous solution010405 organic chemistryGeneral ChemistryMicroporous material0104 chemical sciencesImproved performanceChemistryHighly stableChemical engineeringchemistryTetrathiafulvaleneMetal-organic frameworkCatalystMesoporous materialTetrathiafulvalene
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Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

2016

[EN] Here we present two FeII coordination polymers that possess discrete compartments suitable for CO2 physisorption despite the lack of permanent channels. The two crystalline materials, of general formula [Fe(btzbp)3](X)2 (X = ClO4 or BF4), present voids of ca. 250 Å3, which each can accommodate up to two CO2 molecules. The abrupt spin transition can be modified upon CO2 sorption, and different magnetic behaviour is observed depending on the number of molecules sorbed.

chemistry.chemical_classificationMaterials scienceInorganic chemistryCrystalline materialsSpin transitionSorption02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences3. Good health0104 chemical sciencesInorganic ChemistryPhysisorptionchemistryChemical physicsSpin crossoverMoleculeIsostructural0210 nano-technology
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Cobalt Metal-Organic Framework based on two dinuclear secondary building units for electrocatalytic oxygen evolution

2019

[EN] The synthesis of a new microporous metal-organic framework (MOF) based on two secondary building units, with dinuclear cobalt centers, has been developed. The employment of a well-defined cobalt cluster results in an unusual topology of the Co-2-MOF, where one of the cobalt centers has three open coordination positions, which has no precedent in MOF materials based on cobalt. Adsorption isotherms have revealed that Co-2-MOF is in the range of best CO2 adsorbents among the carbon materials, with very high CO2/CH4 selectivity. On the other hand, dispersion of Co-2-MOF in an alcoholic solution of Nafion gives rise to a composite (Co-2-MOF@Nafion) with great resistance to hydrolysis in aqu…

Materials scienceCobalt clusterLibrary scienceOxygen evolution reaction and gas storage02 engineering and technologyCobalt010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCobalt MOF0104 chemical sciencesQUIMICA ORGANICAQUIMICA ANALITICACobalt metalGeneral Materials Science0210 nano-technologyElectrocatalysisMaterials
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Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process

2013

et al.

Phase transitionMaterials scienceGeneral ChemistryMicroporous materialGeneral MedicineCatalysisX-ray diffractionPropenechemistry.chemical_compoundCrystallographyQUIMICA ORGANICAAdsorptionchemistryChemical engineeringPhase transitionsPropaneFISICA APLICADAScientific methodX-ray crystallographyZeolitesAdsorptionHigh-pressure chemistryZeoliteAngewandte Chemie - International Edition
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Solvent-free synthesis of ZIFs: a route toward the elusive Fe(II) analogue of ZIF-8

2019

Herein we report the synthesis of an elusive metal-organic framework, the iron(II) analogue of ZIF-8 with the formula Fe(2-methylimidazolate) , here denoted as MUV-3. The preparation of this highly interesting porous material, inaccessible by common synthetic procedures, occurs in a solvent-free reaction upon addition of an easily detachable template molecule, yielding single crystals of MUV-3. This methodology can be extended to other metals and imidazolate derivatives, allowing the preparation of ZIF-8, ZIF-67, and the unprecedented iron(II) ZIFs Fe(2-ethylimidazolate) and Fe(2-methylbenzimidazolate) . The different performance of MUV-3 toward NO sorption, in comparison to ZIF-8, results …

Zeolitic imidazolate frameworksStorage02 engineering and technologyOverpotential010402 general chemistryMetal-Organic frameworks01 natural sciencesBiochemistryCatalysischemistry.chemical_compoundColloid and Surface ChemistryImidazolateMaterialsThermal-StabilityTafel equationNanocompositeChemistryOxygen evolutionElectrocatalystsGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesChemisorptionPhysical chemistryMetal-organic frameworkAdsorptionCristalls0210 nano-technologyOxygen evolutionZeolitic imidazolate framework
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Gas confinement in compartmentalized coordination polymers for highly selective sorption

2016

Discrimination between different gases is an essential aspect for industrial and environmental applications involving sensing and separation. Several classes of porous materials have been used in this context, including zeolites and more recently MOFs. However, to reach high selectivities for the separation of gas mixtures is a challenging task that often requires the understanding of the specific interactions established between the porous framework and the gases. Here we propose an approach to obtain an enhanced selectivity based on the use of compartmentalized coordination polymers, named CCP-1 and CCP-2, which are crystalline materials comprising isolated discrete cavities. These compar…

Solucions polimèriquesContext (language use)02 engineering and technologyNeutron scattering010402 general chemistry01 natural sciencescomplex mixturesMolecular dynamicsAdsorptionOrganic chemistryPorositychemistry.chemical_classificationChemistrySorptionQuímicaGeneral ChemistryPolymer021001 nanoscience & nanotechnologyeye diseases3. Good health0104 chemical sciencesChemistry[CHIM.POLY]Chemical Sciences/PolymersChemical engineeringsense organs0210 nano-technologyPorous medium
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CCDC 1473649: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographycatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) diperchlorate carbon dioxide]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1473650: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) diperchlorate ethene]Experimental 3D Coordinates
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CCDC 1440481: Experimental Crystal Structure Determination

2016

Related Article: Néstor Calvo Galve, Mónica Giménez-Marqués, Miguel Palomino, Susana Valencia, Fernando Rey, Guillermo Mínguez Espallargas, Eugenio Coronado|2016|Inorg.Chem.Front.|3|808|doi:10.1039/C5QI00277J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-11'-([11'-biphenyl)-44'-diylbis(methylene)]bis(1H-tetrazole))-iron(ii) bis(tetrafluoroborate)]Experimental 3D Coordinates
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CCDC 1899779: Experimental Crystal Structure Determination

2019

Related Article: Javier López-Cabrelles, Jorge Romero, Gonzalo Abellán, Mónica Giménez-Marqués, Miguel Palomino, Susana Valencia, Fernando Rey, Guillermo Minguez Espallargas|2019|J.Am.Chem.Soc.|141|7173|doi:10.1021/jacs.9b02686

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(bis(mu-2-methylbenzimidazolato)-iron)Cell ParametersExperimental 3D Coordinates
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CCDC 1579606: Experimental Crystal Structure Determination

2018

Related Article: Manuel Souto, Andrea Santiago-Portillo, Miguel Palomino, Iñigo J. Vitórica-Yrezábal, Bruno J. C. Vieira, João C. Waerenborgh, Susana Valencia, Sergio Navalón, Fernando Rey, Hermenegildo García, Guillermo Mínguez Espallargas|2018|Chemical Science|9|2413|doi:10.1039/C7SC04829G

Space GroupCrystallographycatena-((mu-oxo)-hexakis(mu-acetato)-triaqua-tri-iron tris(mu-44'-{2-[45-bis(4-carboxyphenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-bis(mu-oxo)-tetra-aqua-dihydroxy-hexa-iron unknown solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1440482: Experimental Crystal Structure Determination

2016

Related Article: Néstor Calvo Galve, Mónica Giménez-Marqués, Miguel Palomino, Susana Valencia, Fernando Rey, Guillermo Mínguez Espallargas, Eugenio Coronado|2016|Inorg.Chem.Front.|3|808|doi:10.1039/C5QI00277J

catena-[tris(mu-11'-((11'-biphenyl)-44'-diylbis(methylene))bis(1H-tetrazole))-iron bis(tetrafluoroborate)]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825894: Experimental Crystal Structure Determination

2019

Related Article: Javier López-Cabrelles, Jorge Romero, Gonzalo Abellán, Mónica Giménez-Marqués, Miguel Palomino, Susana Valencia, Fernando Rey, Guillermo Minguez Espallargas|2019|J.Am.Chem.Soc.|141|7173|doi:10.1021/jacs.9b02686

Space GroupCrystallographyCrystal Systemcatena-(bis(mu-2-methylimidazolato)-iron unknown solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1439097: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron bis(tetrafluoroborate)]Experimental 3D Coordinates
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CCDC 1439096: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographycatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) bis(tetrafluoroborate)]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1899778: Experimental Crystal Structure Determination

2019

Related Article: Javier López-Cabrelles, Jorge Romero, Gonzalo Abellán, Mónica Giménez-Marqués, Miguel Palomino, Susana Valencia, Fernando Rey, Guillermo Minguez Espallargas|2019|J.Am.Chem.Soc.|141|7173|doi:10.1021/jacs.9b02686

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu-2-ethylimidazolato)-iron)Experimental 3D Coordinates
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CCDC 1473651: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) diperchlorate methane]Experimental 3D Coordinates
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CCDC 1473652: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

catena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) bis(tetrafluoroborate) carbon dioxide]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1473654: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographycatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) bis(tetrafluoroborate) methane]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1898281: Experimental Crystal Structure Determination

2020

Related Article: Silvia Gutiérrez-Tarriño, José Luis Olloqui-Sariego, Juan José Calvente, Miguel Palomino, Guillermo Mínguez Espallargas, José L. Jordá, Fernando Rey, Pascual Oña-Burgos|2019|ACS Applied Materials and Interfaces|11|46658|doi:10.1021/acsami.9b13655

Space GroupCrystallographycatena-[bis(mu-benzene-135-tricarboxylato)-tris(NN-dimethylformamide)-pyridine-tri-cobalt NN-dimethylformamide solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1473653: Experimental Crystal Structure Determination

2017

Related Article: Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado, Guillermo Mínguez Espallargas|2017|Chemical Science|8|3109|doi:10.1039/C6SC05122G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tris(mu-14-bis(1H-tetrazol-1-ylmethyl)benzene)-iron(ii) bis(tetrafluoroborate) ethene]Experimental 3D Coordinates
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