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RESEARCH PRODUCT
A highly stable and hierarchical tetrathiafulvalene-based metal organic framework with improved performance as a solid catalyst
Iñigo J. Vitorica-yrezabalSergio NavalónMiguel PalominoManuel SoutoHermenegildo GarcíaGuillermo Mínguez EspallargasSusana ValenciaJoão C. WaerenborghAndrea Santiago-portilloFernando ReyBruno J. C. Vieirasubject
Solucions polimèriquesMaterials scienceQuímica organometàl·licaCrystal structure010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundQUIMICA ORGANICAMOFAqueous solution010405 organic chemistryGeneral ChemistryMicroporous material0104 chemical sciencesImproved performanceChemistryHighly stableChemical engineeringchemistryTetrathiafulvaleneMetal-organic frameworkCatalystMesoporous materialTetrathiafulvalenedescription
[EN] Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(¿3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-01-01 |