0000000000022258
AUTHOR
S. Basile
Seasonal variation of air kerma rate in Sicily.
Thermoluminescence dosimetry has been used to measure air kerma in 29 sites in Sicily. Four three month measurement campaigns have been carried out in order to assess seasonal variations. Average annual values between 20 and 90 nGy h(-1), after cosmic background subtraction, are reported. Average annual values are strongly dependent on site lithology, and we find that winter data are generally the highest, while spring and autumn rates are generally the lowest with very similar trends in any site. Summer values generally lay in between. Largest seasonal variations are found in sites along the southern coast of the island, probably because of stronger action of winds affecting radon, along w…
Seasonal variation of air kerma in the "Vulcano Porto" area (Aeolian Islands, Italy).
Abstract Air kerma was measured in the “Vulcano Porto” area of the Vulcano Island, belonging to the Aeolian Islands, in the Mediterranean Sea. Measurements were carried out using thermoluminescence dosimeters. The relationship between observed dose values and source lithology has been assessed. Data show a seasonal variation due to weather conditions but also probably related to features of the soils, making the variation more evident.
Gamma activity and geochemical features of building materials: estimation of gamma dose rate and indoor radon levels in Sicily.
A high-purity germanium detector has been used to measure the abundance of radium (Ra), thorium (Th) and potassium (K) in building materials used in Sicilian dwellings. The measurements were performed to evaluate which material was suitable for the construction of an enclosure, which would have a low background emission. The materials examined in this work showed concentrations of 226Ra, 232Th and 40K dramatically variable depending on the lithologies, particularly in the case of blocks, sands and aggregates commonly used in building materials in Sicily. The results are discussed and a criterion is indicated to reduce the radiation dose to humans. Since radon inlet is a major health problem…
Multiphoton-ionization transition amplitudes and the Keldysh approximation.
The Keldysh approximation to treat the multiphoton ionization of atoms is reconsidered. It is shown that, if one consistently uses the hypothesis under which the approximation should be valid (essentially, that of a weak, short-range binding potential), a Keldysh-like term results as an approximation to the first term of a uniformly convergent series in powers of the binding potential. No cancellation occurs when higher-order terms are taken into account. This result allows one to consider the Keldysh approximation as a well-defined theoretical model, without implying, however, that it is adequate to describe multiphoton ionization of real atoms.
"Historical pigments characterisation by quantitative X-ray fluorescence"
Abstract Most of the historical paints are mainly constituted by inorganic pigments, either pure or mixed, spread on the surfaces using different binding agents. The knowledge of the exact amount of different constituents of the paint, as well as of the mixing and pictorial techniques, is crucial for a careful program of conservation of polychrome works. Moreover, since the availability of these pigments has been changing through the centuries, their identification and chemical characterisation is useful to acquire or deepen information about the artist and his/her work. This information can also be useful for authentication purposes through relative dating because the identification of one…
Structural assessment of the EU-DEMO WCLL Central Outboard Blanket segment under normal and off-normal operating conditions
Abstract Within the framework of the EUROfusion design activities concerning the EU-DEMO Breeding Blanket (BB) system, a research campaign has been carried out at the University of Palermo with the aim of investigating the structural behaviour of the DEMO Water-Cooled Lithium Lead (WCLL) Central Outboard Blanket (COB) segment. The assessment has been performed considering three different loading scenarios: the Normal Operation (NO), the Over-Pressurization (OP) and the Upward Vertical Displacement Event (VDE-up). In particular, NO scenario represents the loading case referring to the nominal operating conditions, whereas the OP scenario refers to the loading conditions due to an in-box LOCA…
Analytical evaluation of integrals occurring in bound-free transitions.
A class of three-dimensional integrals on spatial coordinates of the type occurring in treatments of multiphoton ionization of atoms and of other bound-free transitions is evaluated in closed form for both hydrogenic and Slater-type wave functions. The reported method of evaluation is illustrated with a number of examples, including the multiphoton ionization of hydrogen by a very intense laser field, when the ejected electrons have absorbed more photons than the minimum required to reach the continuum.
Distribution of Heavy Metals in Marine Sediments of Palermo Gulf (Sicily, Italy)
Concentrations of Cr, Cu, Hg, Pb and Zn have been measured, by atomic absorption spectrophotometry, in the fine fraction (<63 μm) of surface sediments collected in 30 sites in the Palermo Gulf (Sicily, Italy) in order to assess the levels and the spatial distribution of these elements. Enrichment factors calculated with respect to clean areas have been considered to discriminate between levels due to background or to pollution contributions. The sampling stations, which form a grid inside these areas, are characterized by geographic proximity and by the presence of pollution sources. Ratio matching technique along with hierarchical clustering, minimum spanning tree and principal component a…
Strong-field high-frequency approximation to the multiphoton ionization of hydrogen
The strong-field multiphoton ionization of atoms is considered and a theoretical approach dealing nonperturbatively with the radiation field formulated. The general computational scheme is the conventional perturbation theory, but the intermediate states are dressed by the field. We present in detail a method to dress the continuum states and to study the dipole transitions within the continuum. In the high-frequency domain, the proposed procedure rapidly converges over a wide range of field intensity and offers an interesting framework for calculating ionization rates for arbitrary numbers of absorbed (above-threshold) photons and field polarization.
Joint probability distributions for wind speed and direction. A case study in Sicily
In this study we analyze data of hourly average wind speed and direction measured at three different sampling stations located in Sicily (Italy) and provide a statistical model for their joint probability density function. Singly truncated from below Normal Weibull mixture distribution and a linear combination of von Mises distributions are used to model wind speed and direction. Sites with heterogeneous local conditions (prevailing wind direction and/or elevation) have been considered in order to investigate the reliability of the model here taken into consideration.
Pre-conceptual design of EU-DEMO Divertor primary heat transfer systems
Abstract In the frame of the activities promoted and encouraged by the EUROfusion Power Plant Physics and Technology (PPPT) department aimed at developing the EU-DEMO fusion reactor, strong emphasis has been recently addressed to the whole Balance of Plant (BoP) which represents the set of systems devoted to convert the plasma generated thermal power into electricity and to deliver it to the grid. Among these systems, the Divertor Primary Heat Transfer Systems (PHTSs) are intended to feed coolant to the two main components of the Divertor assembly, namely the Plasma Facing Components (PFCs) and the Cassette Body (CB). Since the DEMO Divertor must withstand high heat flux loads together with…
Energy resolution and throughput of a new real time digital pulse processing system for x-ray and gamma ray semiconductor detectors
New generation spectroscopy systems have advanced towards digital pulse processing (DPP) approaches. DPP systems, based on direct digitizing and processing of detector signals, have recently been favoured over analog pulse processing electronics, ensuring higher flexibility, stability, lower dead time, higher throughput and better spectroscopic performance. In this work, we present the performance of a new real time DPP system for X-ray and gamma ray semiconductor detectors. The system is based on a commercial digitizer equipped with a custom DPP firmware, developed by our group, for on-line pulse shape and height analysis. X-ray and gamma ray spectra measurements with cadmium telluride (Cd…
Production and transport modelling of Po-210 in DEMO reactor
Abstract One of the generic designs of the nuclear fusion DEMO reactor proposed by the EUROfusion consortium foresees the development of a tritium breeding blanket (BB) relying on the use of the liquid-metal PbLi eutectic alloy as both neutron multiplier and tritium breeder, namely the water-cooled lithium lead (WCLL) BB, whose strengths and weaknesses are well known. This paper focuses the attention on one of the possible disadvantages of such a technology: the production of the highly radiotoxic radionuclide 210Po, which could become a safety issue to be accounted for. The 210Po concentration within the PbLi circuit has been assessed by solving a modified version of Bateman’s equations to…
Exposure of -alanine and -ammonium tartrate ESR dosimeters to thermal neutrons: Experiments and Monte Carlo simulations
Abstract Electron spin resonance solid state dosimetry with alanine and ammonium tartrate pellets is a valuable tool in both medical and industrial applications when dealing with photon and charged particle beams. Its use in neutron beams is limited by the low nuclear cross section values of atoms in the pellets. Addition of boron (10B) or gadolinium ( Gd 2 O 3 ) , known to have high neutron capture cross sections, has been proposed to improve neutron sensitivity. In this paper we present the results of an experimental study concerning neutron sensitivity vs. gadolinium concentration in dosimeter mixtures, with the aim of optimizing mixture composition and maximizing the electron spin resol…
Multichannel Multiphoton Ionization of the Hydrogen Atom by a Chaotic Field: Role of the Polarization
This contribution is concerned with the theory of ionization of atoms by strong laser fields, when ionization channels of different photon multiplicity are simultaneously open. Presently, this process is attracting a lot of attention, from both the experimental and theoretical sides.
Analysis and modeling of wind directions time series
This work aims at studying some aspects of wind directions in Italy and supplying appropriate models. A comparison is presented between independent mixture and Hidden Markov models, which seem to be appropriate as far as the series we studied.
Nonperturbative treatments of nonresonant multiphoton ionization of the hydrogen atom: weak-field limit
A nonperturbative treatment of the multiphoton ionization of the hydrogen atom based on the S matrix and devised for nonresonant strong-field situations is analyzed in the weak-field limit. Comparisons are presented with other S matrices as well as other nonperturbative approaches. Our treatment is found to perform generally better than similar S-matrix treatments. The usual perturbative results are recovered provided that the photon wavelengths are sufficiently short and are off resonance with the atomic transitions. Important indications are obtained as to the role of the atomic structure, the relevance of the gauge consistency, and the reliability and improvement of the present nonpertur…
ESR response of watch glasses to proton beams
In this paper we have analyzed the electron spin resonance (ESR) signal of watch glasses irradiated with %60 MeV proton beams in the dose range between 1 and 105 Gy. The composition of samples expressed in oxides weight percentages has been obtained carrying out X-ray fluorescence spectrometry (XRF) mea- surements. The ESR signal has been studied in terms of its dependence on microwave power and modulation field in order to choose the optimal recording parameters. The dependence of the radioinduced signal on the exposure dose has been investigated. A numerical procedure aimed at improving the sensitivity in the low dose range has been developed.
Cyclic influences on the heavy metal chronology in a Central Mediterranean area (Palermo Gulf, Italy)
PurposeThe evaluation of long-term heavy metal concentrations in the Gulf of Palermo (Italy) has been carried out in order to investigate how changes of pollution levels in the last 50 years can be reflected in marine sediments. Measurements of Cr, Cu, Hg, Pb, and Zn concentrations were performed on dated fractions of a sediment core. Time series analysis has allowed to obtain information on the chronology of the heavy metal pollution of the area and to identify seasonal components and trends.Materials and methodsHeavy metal concentrations in the <63 μm fraction of core sections were obtained by Atomic Absorption Spectrophotometry, after wet sieving, drying, and digestion procedures. Dating…
Environmental radioactivity at Stromboli (Aeolian Islands)
HPGe gamma spectrometry, thermoluminescence dosimetry, X-ray diffractometry and fluorescence techniques have been used to analyze the natural radionuclides content of soil and rock samples, air kerma and geochemical features on the island of Stromboli, belonging to the Aeolian Islands, in the Mediterranean Sea. The 214Bi, 238Ac, and 40K contents obtained are in agreement with the magmatic evolution of the rock formation, as shown by the correlations between radionuclide and chemical elements abundacies, depending on the various magmatic differentiation mechanisms. Correlations between radiometric, lithological and geochemical data have been assessed in order to obtain some hints on the geoc…
Multiphoton One-step Ionization of Helium at 1064 nm
Abstract The multiphoton ionization of helium by a strong radiation field having a wavelength of 1064 nm and a field intensity up to 5 × 1014 W cm −2 is considered within a non-perturbative treatment partially accounting for the electron-electron correlations in the initial bound state and approximately for the Coulomb interaction between the residual ion and the ejected electron in the final state. Only single-electron transitions are considered, the main emphasis being on the field polarization effects. The obtained results are compared with the few results available in the literature in the same regime as well as with very recent experimental findings. In particular, the calculated photo…
Thermofluid-dynamic assessment of the EU-DEMO divertor single-circuit cooling option
Until 2019, the thermo-hydraulic development of the EU-DEMO divertor was based on the “double-circuit” concept, in which two independent cooling circuits served by two different Primary Heat Transfer Systems were used to cool the Plasma-Facing Components (PFC) and the Cassette Body (CB). During the Divertor Final Design Review Meeting, held in May 2020, the possibility to adopt a single cooling circuit to serve both components was suggested. This new cooling circuit was originally conceived with the aim of simplifying remote maintenance, with potential benefits for some aspects of safety and balance of plant design and integration. During the years from 2020 to 2022, in the fram…
Mosaic floors of roman Villa del Casale: Principal component analysis on spectrophotometric and colorimetric data
Abstract Spectrophotometric and colorimetric data obtained during a measurement campaign aimed at supporting the Roman "Villa del Casale" (Piazza Armerina, Sicily, Italy) conservation activities, are presented. Special attention was paid to the possible variation of the chromatic coordinates, possibly due to the interventions of cleaning, consolidation, and protection. Data have been analyzed by the Principal Component Analysis (PCA) statistical technique, with the attempt to investigate its role in data variability reduction and verify its effectiveness in interpreting the phenomena occurring on the mosaic surface of the Villa, through grouping the observations into homogenous clusters. Ef…
Chemistry, mineralogy and radioactivity inposidonia oceanicameadows from North-Western Sicily
This paper presents measurements of major, minor, metal trace elements and radionuclides in sediments and in Posidonia oceanica samples from north-western Sicily (Italy). The mineralogical and chemical composition of sediments were determined by X-ray diffraction and X-ray fluorescence techniques, respectively. A flame atomic absorption spectrophotometry was used to measure concentrations of Cu, Zn, Cd and Pb in P. oceanica samples and in sediments. Specific activities of selected radionuclides have been determined by high-resolution gamma spectrometry. Standard statistical analysis was used to assess correlations between different elements and different sample types.
Correlation of radioactivity measurements, air kerma rates and geological features of Sicily
Abstract Sicily, the largest Mediterranean island (with an extension of about 25 000 km 2 ), exhibits a very wide variety of lithologies, ranging from sedimentary to metamorphic and volcanic rocks. Principal component analysis (PCA) and hierarchical cluster analysis (HCA) have been applied to air kerma values measured by thermoluminescent dosimetry in several sites and to data of radionuclide concentrations, geochemical and mineralogical features of rocks and soils sampled in 29 sites of Sicily to point out similarities among different lithologies. The study was devoted to find multiple correlations and allow a better classification of Sicilian lithotypes. Samples of rocks and soils have be…
Monte Carlo simulation of the response of ESR dosimeters added with gadolinium exposed to thermal, epithermal and fast neutrons
Abstract Monte Carlo numerical calculations of the response of alanine and ammonium tartrate ESR (electron spin resonance) dosimeters exposed to neutron fields with different energy spectra are reported. Results have been obtained for various gadolinium concentrations inside the dosimeters. Furthermore, in order to simulate the in-phantom response we have carried out calculations by varying the depth of the dosimeter. We have found that a large enhancement is obtained for thermal neutrons, because of the very high capture cross section of gadolinium to thermal neutrons. A good enhancement was obtained for epithermal neutrons, whereas the sensitivity improvement in the case of fast neutron i…
Dating of a Sediment Core by 210Pbex Method and Pb Pollution Chronology in the Palermo Gulf (Italy)
Within a more general study on marine sediments in the Gulf of Palermo (Sicily, Italy), the 210Pbex dating method (using a model with constant sedimentation rate) has been applied to one sediment core. The main goal of the research was to study the Pb pollution chronology. Dating of the core has allowed evaluating the time evolution of the gulf lead concentrations. Specific activities of 137Cs have also been measured in the sediment core sections as an independent confirmation of the chronology derived by the 210Pbex method. The time scale has then been used to correlate lead concentrations in core sections to estimated lead emissions in air due to gasoline combustion. A good correlation be…
Volcanic products of Lipari (Aeolian islands, Italy): Multivariate analysis of petrographic and radiometric data
Abstract A petrographic and radiometric study, along with statistical multivariate analysis of volcanic products of the island of Lipari (Aeolian islands, Italy) was carried out. The volcanological history of Lipari was reconstructed defining two stages (pre- and post-erosive stages) further on subdivided in four volcanic phases, each of which characterized by products with a particular chemical composition and separated by stratigraphic unconformities. The correlations between petrographic features, determined by X-ray fluorescence, and volcanological history of the island highlight a gradual differentiation with younger rocks showing a more acid chemical composition than the older ones. R…
Thermoluminescence response of sodalime glass irradiated with proton and neutron beams
In the research field of emergency dosimeters to be used in case of accidental radiation exposure of the population, watch glass has been considered as a possible fortuitous dosimetric material. This paper reports on results obtained by thermoluminescence of glass samples exposed to neutron and proton beams. Thermoluminescent glow curves have been analyzed for each irradiation studying the modifications induced by the irradiation as a function of proton dose or neutron fluence. The glow curve in a specific temperature range has been used as dosimetric parameter. The thermoluminescence response of samples exposed to protons has been found to be linear in the dose range between 2 and 20 Gy an…
Analysis of 7Be and 210Pb concentration and 7Be/210Pb activity ratio in ground level air in Palermo (Italy)
A series of measurements of particulate samples collected on paper filters in Palermo (Italy) during 1995–2005 has been performed to detect 210Pb air activity concentration and, along with previous similar data on 7Be, to evaluate their activity ratio. Average values for the daily activity concentrations of 7Be and 210Pb are found to be 4.7 and 0.6 mBq/m3 , respectively, 9.8 being the average activity ratio. Data confirm a seasonal behavior for both radionuclides. A correlation between 7Be and 210Pb air activity concentrations seems to exist, despite their different origins. The time behaviors of both 7Be and 210Pb air concentrations and 7Be/ 210Pb activity ratio have been compared with som…