0000000000022284
AUTHOR
Jasmin Jakupovic
Jatrophane derivatives and a rearranged jatrophane from Euphorbia terracina
Abstract The aerial parts of Euphorbia terracina yielded 11 new jatrophane derivatives as well as a further diterpene displaying the novel 1(15 → 14) abeo -jatrophane framework.
New sesquiterpene lactones and acetylenes from chrysanthemum lavandulifolium
Abstract The aerial parts of Chrysanthemum lavandulifolium Mak. (Asteraceae) yielded three new acetylenes of the spiroacetal type 1-3, as well as two new germacranolides 4-5 and several known lactones.
Terracinolides from Euphorbia terracina
Abstract The aerial parts of Euphorbia terracina yielded five new bishomoditerpene lactones, named terracinolides C-G, which display the novel C 22 17-ethyljatrophane framework.
Diterpenes from Euphorbia paralias
Abstract Chemical investigation of Euphorbia paralias from Spain afforded 13 diterpenes of different structual types, including one with a novel skeleton.
A novel germacranolide-aminoacid adduct dimer from centaurea aspera
Abstract The novel germacronolide-valine adduct dimer 1 has been isolated from aerial parts of Centaurea aspera var. aspera . Its structure has been determined by spectroscopic methods.
Diterpenes from Euphorbia segetalis
Numerous new diterpenes including several with new skeletons have been obtained from Euphorbia segetalis.
New oxygenated eudesmanolides from artemisia herba-alba
Abstract The aerial parts of Artemisia herba-alba Asso subsp.valentina Lam. (Asteraceae) yielded the new eudesmanolides 1-11 and the new sesquiterpene-monoterpene adducts 12-13. The absolute configuration of compound 6 was confirmed with the aid of X-ray diffraction analysis. Some aspects of the thermal and photochemical reactivity of 2,4-cyclohexadienones are discussed.
Sesquiterpene lactones fromArtemisia barrelieri
Abstract Extraction of aerial parts of Artemisia barrelieri and chromatographic separation yielded a new germacranolide, two new monocyclic sesquiterpenes and a novel germacranolide dimer, together with several known compounds.