Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer
We present a structurally flexible copper–iodide–pyridine-based coordination polymer showing drastic variations in its electrical conductivity driven by temperature and sorption of acetic acid molecules. The dramatic effect on the electrical conductivity enables the fabrication of a simple and robust device for gas detection. X-ray diffraction studies and DFT calculations allow the rationalisation of these observations.
Heteroatom Effect on Star-Shaped Hole-Transporting Materials for Perovskite Solar Cells
Halo and Pseudohalo Cu(I)-Pyridinato Double Chains with Tunable Physical Properties
The properties recently reported on the Cu(I)-iodide pyrimidine nonporous 1D-coordination polymer [CuI(ANP)] (ANP = 2-amino-5-nitropyridine) showing reversible physically and chemically driven electrical response have prompted us to carry a comparative study with the series of [CuX(ANP)] (X = Cl (1), X = Br (2), X = CN (4), and X = SCN (5)) in order to understand the potential influence of the halide and pseudohalide bridging ligands on the physical properties and their electrical response to vapors of these materials. The structural characterization of the series shows a common feature, the presence of -X-Cu(ANP)-X- (X = Cl, Br, I, SCN) double chain structure. Complex [Cu(ANP)(CN)] (4) pre…
Experimental and Theoretical Study of Dynamic Structural Transformations between Sensing Copper(II)-Uracil Antiferromagnetic and Metamagnetic Coordination Compounds
This paper describes the synthesis and characterization of several Copper(II)-uracil-1-propionic acid (UPrOH) coordination compounds, including the theoretical and experimental study of their cryst...
Perovskite Solar Cells: Heteroatom Effect on Star-Shaped Hole-Transporting Materials for Perovskite Solar Cells (Adv. Funct. Mater. 31/2018)
Structure and Properties of One-Dimensional Heterobimetallic Polymers Containing Dicyanoaurate and Dirhodium(II) Fragments
The synthesis and characterization of compound [Rh(2)(O(2)CEt)(4)(H(2)O)(2)] (1) and one-dimensional heterobimetallic polymers K(n){Rh(2)(O(2)CEt)(4)[Au(CN)(2)]}(n) (2) and K(n){Rh(2)(O(2)CMe)(4)[Au(CN)(2)]}(n)·4nH(2)O (3), constructed from dirhodiumtetracarboxylato units, [Rh(2)(O(2)CR)(4)](+), and dicyanoaurate, [Au(CN)(2)](-), fragments are described. In both compounds 2 and 3 the resulting polymeric chains are nonlinear and have in common similar structural parameters, although the solid state supramolecular arrangement is very different. These structural differences explain the fact that complex 2 displays aurophilic interactions while this type of interactions are absent in complex 3.…
Coordination polymers based on diiron tetrakis(dithiolato) bridged by alkali metals, electrical bistability around room temperature, and strong antiferromagnetic coupling.
Coordination polymer chains have been formed by the direct reaction between HSC6H2Cl2SH and FeCl3·6H2O in the presence of an aqueous solution of the corresponding alkali-metal hydroxide (M = Li, Na, and K) or carbonate (M = Rb and Cs). The structures consist of dimeric [Fe2(SC6H2Cl2S)4](2-) entities bridged by [M2(THF)4] [M = K (1), Rb (2), and Cs (3); THF = tetrahydrofuran] or {[Na2(μ-H2O)2(THF)2] (5 and 5') units. The smaller size of the lithium atom yields an anion/cation ion-pair molecule, [Li(THF)4]2[Fe2(SC6H2Cl2S)4] (4), in which the dianionic moieties are held together by Cl···Cl interactions. Electrical characterization of these compounds shows a general semiconductor behavior in wh…
CCDC 1979325: Experimental Crystal Structure Determination
Related Article: Noelia Maldonado, Josefina Perles, José Ignacio Martínez, Carlos J. Gómez-García, María-Luisa Marcos, Pilar Amo-Ochoa|2020|Cryst.Growth Des.|20|5097|doi:10.1021/acs.cgd.0c00268
CCDC 1979323: Experimental Crystal Structure Determination
Related Article: Noelia Maldonado, Josefina Perles, José Ignacio Martínez, Carlos J. Gómez-García, María-Luisa Marcos, Pilar Amo-Ochoa|2020|Cryst.Growth Des.|20|5097|doi:10.1021/acs.cgd.0c00268
CCDC 1813461: Experimental Crystal Structure Determination
Related Article: Inés García-Benito, Iwan Zimmermann, Javier Urieta-Mora, Juan Aragó, Joaquín Calbo, Josefina Perles, Alvaro Serrano, Agustín Molina-Ontoria, Enrique Ortí, Nazario Martín, Mohammad Khaja Nazeeruddin|2018|Adv.Energy Mater.|28|1801734|doi:10.1002/adfm.201801734
CCDC 1979326: Experimental Crystal Structure Determination
Related Article: Noelia Maldonado, Josefina Perles, José Ignacio Martínez, Carlos J. Gómez-García, María-Luisa Marcos, Pilar Amo-Ochoa|2020|Cryst.Growth Des.|20|5097|doi:10.1021/acs.cgd.0c00268
CCDC 1054832: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1054830: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1054827: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1979324: Experimental Crystal Structure Determination
Related Article: Noelia Maldonado, Josefina Perles, José Ignacio Martínez, Carlos J. Gómez-García, María-Luisa Marcos, Pilar Amo-Ochoa|2020|Cryst.Growth Des.|20|5097|doi:10.1021/acs.cgd.0c00268
CCDC 1054831: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1813460: Experimental Crystal Structure Determination
Related Article: Inés García-Benito, Iwan Zimmermann, Javier Urieta-Mora, Juan Aragó, Joaquín Calbo, Josefina Perles, Alvaro Serrano, Agustín Molina-Ontoria, Enrique Ortí, Nazario Martín, Mohammad Khaja Nazeeruddin|2018|Adv.Energy Mater.|28|1801734|doi:10.1002/adfm.201801734
CCDC 1054829: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1813459: Experimental Crystal Structure Determination
Related Article: Inés García-Benito, Iwan Zimmermann, Javier Urieta-Mora, Juan Aragó, Joaquín Calbo, Josefina Perles, Alvaro Serrano, Agustín Molina-Ontoria, Enrique Ortí, Nazario Martín, Mohammad Khaja Nazeeruddin|2018|Adv.Energy Mater.|28|1801734|doi:10.1002/adfm.201801734
CCDC 1979322: Experimental Crystal Structure Determination
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CCDC 1054828: Experimental Crystal Structure Determination
Related Article: Samia Benmansour , Esther Delgado , Carlos J. Gómez-García , Diego Hernández , Elisa Hernández , Avelino Martin , Josefina Perles , and Félix Zamora|2015|Inorg.Chem.|54|2243|doi:10.1021/ic502789v
CCDC 1977195: Experimental Crystal Structure Determination
Related Article: Noelia Maldonado, Josefina Perles, Pilar Amo-Ochoa|2020|CSD Communication|||