6533b829fe1ef96bd128b035
RESEARCH PRODUCT
Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer
Samia BenmansourOscar CastilloJosefina PerlesFélix ZamoraCarlos J. Gómez-garcíaPilar Amo-ochoaKhaled HassaneinJosé I. MartínezPilar Ocónsubject
chemistry.chemical_classificationFabricationChemistryCoordination polymerIodideMetals and AlloysNanotechnologySorptionQuímicaGeneral ChemistryAcetic acidPhotochemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundAcetic acidCopper iodide pyridine coordination polymerElectrical resistivity and conductivityPyridineMaterials ChemistryCeramics and CompositesMoleculedescription
We present a structurally flexible copper–iodide–pyridine-based coordination polymer showing drastic variations in its electrical conductivity driven by temperature and sorption of acetic acid molecules. The dramatic effect on the electrical conductivity enables the fabrication of a simple and robust device for gas detection. X-ray diffraction studies and DFT calculations allow the rationalisation of these observations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-01-01 | Chemical Communications |