0000000000011911

AUTHOR

José I. Martínez

showing 21 related works from this author

Electrical conductivity and strong luminescence in copper Iodide double chains with isonicotinato derivatives

2015

Direct reactions between CuI and isonicotinic acid (HIN) or the corresponding esters, ethyl isonicotinate (EtIN) or methyl isonicotinate (MeIN), give rise to the formation of the coordination polymers [CuI(L)] with L=EtIN (1), MeIN (2) and HIN (3). Polymers 1-3 show similar structures based on a CuI double chain in which ethyl-, methyl isonicotinate or isonicotinic acid are coordinated as terminal ligands. Albeit, their supramolecular architecture differs considerably, affecting the distances and angles of the central CuI double chains and thereby their physical properties. Hence, the photoluminescence shows remarkable differences; 1 and 2 show a strong yellow emission, whereas 3 displays a…

Models MolecularThermogravimetric analysisPhotoluminescenceLuminescencePolymersInorganic chemistrySupramolecular chemistrychemistry.chemical_elementConductivityIsonicotinic acidLigandsNiacinCatalysisCopper iodidechemistry.chemical_compoundCoordination ComplexesElectrical conductivityCarboxylateMolecular StructureStructure elucidationOrganic ChemistryElectric ConductivityGeneral ChemistryIodidesCopperCoordination polymersCrystallographychemistryLuminescenceCopper
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Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

2012

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.

Solventchemistry.chemical_compoundMaterials scienceChemical engineeringchemistryMechanics of MaterialsCoordination polymerMechanical EngineeringDelaminationGeneral Materials ScienceComposite materialLayered structureAdvanced Materials
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Smart composite films of nanometric thickness based on copper-iodine coordination polymers. Toward sensors.

2018

One-pot reactions between CuI and methyl or methyl 2-amino-isonicotinate give rise to the formation of two coordination polymers (CPs) based on double zig-zag Cu2I2 chains. The presence of a NH2 group in the isonicotinate ligand produces different supramolecular interactions affecting the Cu-Cu distances and symmetry of the Cu2I2 chains. These structural variations significantly modulate their physical properties. Thus, both CPs are semiconductors and also show reversible thermo/mechanoluminescence. X-ray diffraction studies carried out under different temperature and pressure conditions in combination with theoretical calculations have been used to rationalize the multi-stimuli-responsive …

Materials scienceFabricationPolymersThin filmsComposite numberSupramolecular chemistryNanocomposite films02 engineering and technologyOptoelectronic devices010402 general chemistry01 natural sciencesNanomaterialschemistry.chemical_classificationFilm thicknessChainsNanostructured materialsQuímicaGeneral ChemistryPolymerBinary alloys021001 nanoscience & nanotechnology0104 chemical sciencesChemistrychemistryChemical engineeringNanofiberNanometreFilm preparationSupramolecular chemistry0210 nano-technologyCoordination reactionsNanofibresCopperMechanoluminescenceIodineChemical science
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Back Cover: Electrical Conductivity and Strong Luminescence in Copper Iodide Double Chains with Isonicotinato Derivatives (Chem. Eur. J. 48/2015)

2015

Electrical resistivity and conductivityChemistryOrganic ChemistryInorganic chemistryCover (algebra)General ChemistryLuminescenceCatalysisCopper iodideChemistry - A European Journal
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Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer

2015

We present a structurally flexible copper–iodide–pyridine-based coordination polymer showing drastic variations in its electrical conductivity driven by temperature and sorption of acetic acid molecules. The dramatic effect on the electrical conductivity enables the fabrication of a simple and robust device for gas detection. X-ray diffraction studies and DFT calculations allow the rationalisation of these observations.

chemistry.chemical_classificationFabricationChemistryCoordination polymerIodideMetals and AlloysNanotechnologySorptionQuímicaGeneral ChemistryAcetic acidPhotochemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundAcetic acidCopper iodide pyridine coordination polymerElectrical resistivity and conductivityPyridineMaterials ChemistryCeramics and CompositesMoleculeChemical Communications
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Halo and Pseudohalo Cu(I)-Pyridinato Double Chains with Tunable Physical Properties

2015

The properties recently reported on the Cu(I)-iodide pyrimidine nonporous 1D-coordination polymer [CuI(ANP)] (ANP = 2-amino-5-nitropyridine) showing reversible physically and chemically driven electrical response have prompted us to carry a comparative study with the series of [CuX(ANP)] (X = Cl (1), X = Br (2), X = CN (4), and X = SCN (5)) in order to understand the potential influence of the halide and pseudohalide bridging ligands on the physical properties and their electrical response to vapors of these materials. The structural characterization of the series shows a common feature, the presence of -X-Cu(ANP)-X- (X = Cl, Br, I, SCN) double chain structure. Complex [Cu(ANP)(CN)] (4) pre…

chemistry.chemical_classificationPyrimidineHydrogen bondChemistrySupramolecular chemistryHalideNanotechnologySingle chainPolymerInorganic ChemistryDouble chainchemistry.chemical_compoundCrystallographyPhysical and Theoretical ChemistryLuminescenceInorganic Chemistry
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Experimental and Theoretical Study of Dynamic Structural Transformations between Sensing Copper(II)-Uracil Antiferromagnetic and Metamagnetic Coordin…

2020

This paper describes the synthesis and characterization of several Copper(II)-uracil-1-propionic acid (UPrOH) coordination compounds, including the theoretical and experimental study of their cryst...

chemistry.chemical_classificationMaterials sciencechemistry.chemical_elementUracil02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesCopper0104 chemical sciencesCoordination complexCharacterization (materials science)chemistry.chemical_compoundCrystallographychemistryAntiferromagnetismGeneral Materials Science0210 nano-technologyCrystal Growth & Design
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Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations

2017

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.7b01775

Metal saltsCoordination polymerPotassiumInorganic chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesInorganic ChemistryMetalchemistry.chemical_compoundFirst-principles calculationsGroup (periodic table)Physical and Theoretical ChemistryBenzenechemistry.chemical_classification010405 organic chemistryChemistryPolymerQuímica0104 chemical sciencesCoordination polymersCrystallographyMetal-dithiolene polymersvisual_artvisual_art.visual_art_mediumCoordination compoundsPlatinum
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Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer (Adv. Mater. 15/2013)

2013

Solventchemistry.chemical_compoundMaterials sciencechemistryMechanics of MaterialsCoordination polymerMechanical EngineeringDelaminationGeneral Materials ScienceComposite materialAdvanced Materials
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CCDC 883365: Experimental Crystal Structure Determination

2013

Related Article: Almudena Gallego, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J. Gómez-García, Eva Mateo-Martí, José I. Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora|2013|Adv.Mater.|25|2141|doi:10.1002/adma.201204676

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu2- 22'-Disulfanediyldipyrimidine)-(mu2-chloro)-copper methanol solvate]Experimental 3D Coordinates
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CCDC 1047310: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-iodo)-(isonicotinic acid)-copper(i)]Experimental 3D Coordinates
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CCDC 883368: Experimental Crystal Structure Determination

2013

Related Article: Almudena Gallego, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J. Gómez-García, Eva Mateo-Martí, José I. Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora|2013|Adv.Mater.|25|2141|doi:10.1002/adma.201204676

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(mu~3~-chloro)-tetrakis(22'-disulfanediyldipyrimidine)-tetra-copper(i)
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CCDC 1401258: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal Systemcatena-[(mu-iodo)-(mu-methyl isonicotinate)-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1551942: Experimental Crystal Structure Determination

2017

Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, José I. Martínez, and Félix Zamora|2017|Inorg.Chem.|56|11810|doi:10.1021/acs.inorgchem.7b01775

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-aqua)-bis(mu-benzene-12-dithiolato)-nickel-di-potassium]Experimental 3D Coordinates
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CCDC 1047311: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal Systemcatena-[(mu-iodo)-(mu-methyl isonicotinate)-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1403318: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-iodo)-(methyl isonicotinate)-copper(i)]Experimental 3D Coordinates
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CCDC 1551944: Experimental Crystal Structure Determination

2017

Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, José I. Martínez, and Félix Zamora|2017|Inorg.Chem.|56|11810|doi:10.1021/acs.inorgchem.7b01775

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(bis(mu-benzene-12-dithiolato)-bis(mu-tetrahydrofuran)-platinum-di-potassium)
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CCDC 1047309: Experimental Crystal Structure Determination

2015

Related Article: Khaled Hassanein, Javier Conesa-Egea, Salome Delgado, Oscar Castillo, Samia Benmansour, José I. Martínez, Gonzalo Abellán, Carlos J. Gómez-García, Félix Zamora, Pilar Amo-Ochoa|2015|Chem.-Eur.J.|21|17282|doi:10.1002/chem.201502131

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu-iodo)-(ethyl isonicotinate)-copper(i)]Cell ParametersExperimental 3D Coordinates
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CCDC 883367: Experimental Crystal Structure Determination

2013

Related Article: Almudena Gallego, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J. Gómez-García, Eva Mateo-Martí, José I. Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora|2013|Adv.Mater.|25|2141|doi:10.1002/adma.201204676

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu~2~-22'-Disulfanediyldipyrimidine)-(mu~2~-chloro)-copper ethanol solvate]Cell ParametersExperimental 3D Coordinates
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CCDC 1551943: Experimental Crystal Structure Determination

2017

Related Article: Oscar Castillo, Esther Delgado, Carlos J. Gómez-García, Diego Hernández, Elisa Hernández, Avelino Martín, José I. Martínez, and Félix Zamora|2017|Inorg.Chem.|56|11810|doi:10.1021/acs.inorgchem.7b01775

Space GroupCrystallographydi-potassium bis(benzene-12-dithiolato)-palladium tetrahydrofuran solvate dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 883366: Experimental Crystal Structure Determination

2013

Related Article: Almudena Gallego, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J. Gómez-García, Eva Mateo-Martí, José I. Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora|2013|Adv.Mater.|25|2141|doi:10.1002/adma.201204676

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(mu~2~- 22'-Disulfanediyldipyrimidine)-(mu~2~-chloro)-copper monohydrate]
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