6533b7d2fe1ef96bd125e1dc

RESEARCH PRODUCT

Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

Julio Gómez-herreroIsadora BerlangaCristina Gómez-navarroEva Mateo-martíJosé I. MartínezFélix ZamoraCarlos J. Gómez-garcíaCristina HermosaSalomé DelgadoFernando FloresOscar CastilloAlmudena Gallego

subject

Solventchemistry.chemical_compoundMaterials scienceChemical engineeringchemistryMechanics of MaterialsCoordination polymerMechanical EngineeringDelaminationGeneral Materials ScienceComposite materialLayered structure

description

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.

https://doi.org/10.1002/adma.201204676