0000000000027161
AUTHOR
A. Wiedenmann
Small angle scattering study of poly(methylmethacrylate)-block-poly(ethylene oxide) block co-polymer in aqueous solution
A combined Small Angle X ray (SAXS) and Neutron (SANS) Scattering study of aqueous solutions of a symmetric block copolymer consisting of poly(methyl methacrylate) (PMMA) and poly(ethylene oxide) (PEO) moieties is presented. The polymer forms slightly polydisperse spherical micelles in a wide range of concentration (0.03 – 6.7 w/V) and temperature (20°C ≤ T ≤ 65°C). A good description of the SANS data is obtained using a polydisperse core-shell model with a structure factor for a modified hard sphere potential. By increasing the concentration at constant T we observed a decrease of the aggregation number and an increase of solvation of PEO groups in the shell, opposite to what happens by in…
The structure of high-performance polymer blends by small-angle neutron scattering
Abstract Amorphous blends from a deuterated polyaryletherketone and a polyetherimide have been prepared and investigated by small-angle neutron scattering (SANS). The blends are combinatorial mixtures: the scattering quantity Φ1Φ2/S(q) is independant of the composition of the blends.
SANS polarization analysis at V4 SANS instrument of HMI Berlin
The V4 instrument has recently been upgraded with a 3He spin filter cell, placed directly in the homogeneous field B of the sample magnet, to enhance the SANSPOL option for polarization analysis. The prototype setup was still affected by: (a) a quick relaxation of the 3He nuclear polarization in the cell with a time constant of only ?130 min which significantly changes the spin filter transmissions T+ and T? for neutrons polarized parallel I+ and anti-parallel I? to B, and (b) the absence of a flipping aid behind the sample. The usual polarization analysis procedure, expecting virtually time-independent transmissions and a second flipping device, is therefore not applicable. We present an a…