0000000000039752
AUTHOR
Junghyun Noh
Dynamic tuning of the director field in liquid crystal shells using block copolymers
When an orientationally ordered system, like a nematic liquid crystal (LC), is confined on a self-closing spherical shell, topological constraints arise with intriguing consequences that depend critically on how the LC is aligned in the shell. We demonstrate reversible dynamic tuning of the alignment, and thereby the topology, of nematic LC shells stabilized by the nonionic amphiphilic block copolymer Pluronic F127. Deep in the nematic phase, the director (the average molecule orientation) is tangential to the interface, but upon approaching the temperature TNI of the nematic– isotropic transition, the director realigns to normal. We link this to a delicate interplay between an interfacial …
Tuning the defect configurations in nematic and smectic liquid crystalline shells
Thin liquid crystalline shells surrounding and surrounded by aqueous phases can be conveniently produced using a nested capillary microfluidic system, as was first demonstrated by Fernandez-Nieves et al. in 2007. By choosing particular combinations of stabilizers in the internal and external phases, different types of alignment, uniform or hybrid, can be ensured within the shell. Here, we investigate shells in the nematic and smectic phases under varying boundary conditions, focusing in particular on textural transformations during phase transitions, on the interaction between topological defects in the director field and inclusions in the liquid crystal (LC), and on the possibility to rel…
ChemInform Abstract: Tuning the Defect Configurations in Nematic and Smectic Liquid Crystalline Shells
Thin liquid crystalline shells surrounding and surrounded by aqueous phases can be conveniently produced using a nested capillary microfluidic system, as was first demonstrated by Fernandez-Nieves et al. in 2007. By choosing particular combinations of stabilizers in the internal and external phases, different types of alignment, uniform or hybrid, can be ensured within the shell. Here, we investigate shells in the nematic and smectic phases under varying boundary conditions, focusing in particular on textural transformations during phase transitions, on the interaction between topological defects in the director field and inclusions in the liquid crystal (LC), and on the possibility to relo…
Tuneable multicoloured patterns from photonic cross-communication between cholesteric liquid crystal droplets
Monodisperse droplets of planar-aligned cholesteric (N*) liquid crystal exhibit an intriguing capacity for photonic cross-communication, giving rise to colourful patterns that depend sensitively on the N* pitch, droplet positions and illuminated area. The phenomenon results from a combination of omnidirectional selective reflection of N* droplets—which thus act as spherically symmetric self-assembled photonic crystals—and total internal reflection at the continuous phase surface. We outline how the unique optical properties can be employed in numerous applications.
Dynamic tuning of the director field in liquid crystal shells using block copolymers
When a nematic liquid crystal (LC) is confined on a self-closing spherical shell, topological constraints arise with intriguing consequences that depend critically on how the LC is aligned in the shell. We demonstrate reversible dynamic tuning of the alignment, and thereby the topology, of nematic LC shells stabilized by the nonionic amphiphilic block copolymer Pluronic F127. Deep in the nematic phase, the director is tangential to the interface, but upon approaching the temperature TNI of the nematic-isotropic transition, the director realigns to normal. We link this to a delicate interplay between an interfacial tension that is nearly independent of director orientation, and the configura…