0000000000046654
AUTHOR
Giovanni Gigante
Identification Techniques I
Infrared (IR) and Raman spectroscopy have a high potential for characterisation of material. Extensive series of wet chemical analysis may be substituted by a single spectroscopic measurement followed by detailed chemometric data evaluation. Topics of this chapter are: (i) basics of IR and Raman spectroscopy, (ii) the registration of “correct” spectra, and (iii) spectra evaluation. Dedicated applications in the area of conservation science are collected in separate chapters. The infrared (IR) spectrum is often called the fingerprint of a substance. An IR spectrum identifies a substance like a human fingerprint. Due to their origin the features of an IR spectrum are bands, not peaks. They in…
The use of a European coinage alloy to compare the detection limits of mobile XRF systems. A feasibility study
The investigation of archaeological and historical materials makes use of techniques that, though borrowed from other fields of research and industrial production, frequently have to be 're-invented' because of peculiar characteristics of the analysed objects. Artistic relevance, limited movability, compositional and structural heterogeneity radically change the experimental approach and often require ad hoc designed equipment. These considerations also apply to x-ray fluorescence, especially regarding mobile systems. The extensive development and use of mobile spectrometers has produced an extremely diversified context and created the need for common criteria to evaluate their performances…