Bio-based rigid high-density polyurethane foams as a structural thermal break material

Abstract Sustainable development of building industry implies increasing usage of green materials. With this aim and for the intended application as a structural thermal break material, rigid high-density polyurethane foams have been manufactured using polyols derived from renewable resources - tall oil fatty acids. Thermal conductivity, compressive strength and stiffness of the foams of density ranging from ca. 100 to 680 kg/m3 have been determined. Comparison of the bio-based foams with reference foams derived from petrochemical resources demonstrated similar performance characteristics thus suggesting that bio-based foams can also serve as structural thermal break materials. Analytical m…

Estimation of the effective diffusivity of blowing agents in closed-cell low-density polyurethane foams based on thermal aging data

Abstract Low-density closed-cell polyurethane (PU) foams are applied as thermal insulation materials due to their low thermal conductivity imparted by that of the physical blowing agent (PBA) used in foam production. However, foam conductivity tends to gradually increase with time, primarily due to changes in the gas composition in foam cells brought about by gas diffusion. To enable predicting the variation of conductivity during the service life of foam insulation, gas diffusivities are usually determined by measuring the gas composition in foams at different aging times. This study considers an alternative approach of estimating the effective diffusivities of gases in PU foams, which is …

Rigid Closed‐Cell PUR Foams Containing Polyols Derived from Renewable Resources: The Effect of Polymer Composition, Foam Density, and Organoclay Filler on Their Mechanical Properties