0000000000048318
AUTHOR
J. V. Yakhmi
showing 2 related works from this author
Reversible dehydration polymerization of terephthalate bridged [{Cu2(2,2′-bpy)2(tp)(H2O)3(NO3)}·H2O·NO3]2
2006
The title compound is the first example of a molecular magnet sponge, which exhibits a carboxylate-assisted unique reversible dehydrative polymerization–rehydrative monomerization phenomenon.
Syntheses and crystal structures of three novel Cu(II) coordination polymers of different dimensionality constructed from Cu(II) carboxylates (carbox…
2004
Abstract We herein report three new coordination polymers generated from Cu(II) carboxylates (mal, 2ac, fum) and conformationally flexible bifunctional IX as building blocks. All the three complexes adopt unique structures in the solid state. The complex [Cu2(mal)2(IX)2(H2O)6]n crystallizes as orthorhombic co-linear rods with space group P2(1) P2(1) P2(1). Each rod is further formed of two tightly intertwined strings. The second polymer [Cu2(ac)4(IX)2]n crystallizes with space group P1 which consists of two sets of intersecting 2D sheets composed of parallel rods which interpenetrate to form a fully interlocked 3D structure. In both these complexes IX coordinates in the anti mode. The third…