0000000000049449

AUTHOR

Jun Hyuk Chang

showing 2 related works from this author

The Role of Emission Layer Morphology on the Enhanced Performance of Light-Emitting Diodes Based on Quantum Dot-Semiconducting Polymer Hybrids

2016

The influence of the morphology of quantum dot (QD)-semiconducting polymer hybrid emission layers on the performance of quantum dot-based light emitting diodes (QLEDs) is systematically investigated. Chemically grafted QD-semiconducting polymer hybrids are fabricated by the ligand exchange procedure between CdSe/CdxZn1−xS QDs and a new block copolymer consisting of a carbazole-based electroactive block with a low highest occupied molecular orbital level and a disulfide-based anchor block. The performance of QLEDs with hybrid emission layers is compared with QLEDs utilizing QD-only and physically mixed QD/polymer emission layers. It is shown that only in the emission layers formed by chemica…

chemistry.chemical_classificationConductive polymerMaterials sciencebusiness.industryCarbazoleMechanical Engineering02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceslaw.inventionchemistry.chemical_compoundchemistryMechanics of MaterialsQuantum dotlawOptoelectronicsQuantum efficiency0210 nano-technologybusinessHybrid materialHOMO/LUMOLight-emitting diodeAdvanced Materials Interfaces
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Side-chain conjugated polymers for use in the active layers of hybrid semiconducting polymer/quantum dot light emitting diodes

2016

Three monomers, M1–M3, with modified carbazole cores and styrene functionality were prepared for use in the active layers of hybrid polymer/quantum dot light emitting diodes. Utilizing reversible addition fragmentation chain transfer polymerization, side-chain conjugated polymers, P1–P3, with narrow polydispersities and disulfide end groups were obtained. The thermal, optical, and electrochemical properties of the polymers varied depending on the substituents of the carbazole cores. Through the disulfide end groups the polymers were chemically blended with quantum dots to obtain QD/polymer hybrids, which were further used as active layers in light emitting diodes. The fabricated devices ret…

chemistry.chemical_classificationMaterials sciencePolymers and PlasticsCarbazolebusiness.industryOrganic ChemistryBioengineeringChain transfer02 engineering and technologyPolymerElectroluminescence010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistry0104 chemical scienceschemistry.chemical_compoundchemistryPolymerizationQuantum dotSide chainOptoelectronicsQuantum efficiency0210 nano-technologybusinessPolymer Chemistry
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