6533b7cefe1ef96bd1257964
RESEARCH PRODUCT
The Role of Emission Layer Morphology on the Enhanced Performance of Light-Emitting Diodes Based on Quantum Dot-Semiconducting Polymer Hybrids
Ana FokinaWan Ki BaeJun Hyuk ChangJun Hyuk ChangYeonkyung LeeKookheon CharChanghee LeeYounghun SungRudolf ZentelMyeongjin Parksubject
chemistry.chemical_classificationConductive polymerMaterials sciencebusiness.industryCarbazoleMechanical Engineering02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceslaw.inventionchemistry.chemical_compoundchemistryMechanics of MaterialsQuantum dotlawOptoelectronicsQuantum efficiency0210 nano-technologybusinessHybrid materialHOMO/LUMOLight-emitting diodedescription
The influence of the morphology of quantum dot (QD)-semiconducting polymer hybrid emission layers on the performance of quantum dot-based light emitting diodes (QLEDs) is systematically investigated. Chemically grafted QD-semiconducting polymer hybrids are fabricated by the ligand exchange procedure between CdSe/CdxZn1−xS QDs and a new block copolymer consisting of a carbazole-based electroactive block with a low highest occupied molecular orbital level and a disulfide-based anchor block. The performance of QLEDs with hybrid emission layers is compared with QLEDs utilizing QD-only and physically mixed QD/polymer emission layers. It is shown that only in the emission layers formed by chemically grafted hybrids QDs are evenly distributed throughout the semiconducting polymer matrix. This leads to improved charge transport balance and suppressed photoluminescence quenching of QDs. As a result, hybrid QLEDs with the peak external quantum efficiency of 5.6% and the peak luminance of 21 707 cd m−2 which outperform the conventional devices with QD-only emission layers are fabricated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-07-11 | Advanced Materials Interfaces |