0000000000049928

AUTHOR

V. Nicolı̀

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Effect of Gold on the HDS Activity of Supported Palladium Catalysts

2002

Abstract The effect of gold on palladium catalysts supported on amorphous aluminosilicate was investigated in the hydrodesulfurization of thiophene. A series of bimetallic AuxPdy catalysts was prepared by the slow deposition–precipitation method with decomposition of urea. The structural and surface properties of the samples were analyzed by X-ray diffraction and X-ray photoelectron spectroscopy techniques at different stages of the catalyst life. After calcination at 673 K, gold-enriched solid solutions of approximately Au90Pd10 and Au80Pd20 composition were formed for all samples of different Au/Pd ratios, along with free palladium phases. Au80Pd20 was the prevailing phase. Hydrogen treat…

Inorganic chemistrychemistry.chemical_elementHeterogeneous catalysisCatalysislaw.inventionCatalysisMetalchemistry.chemical_compoundchemistrylawvisual_artThiophenevisual_art.visual_art_mediumCalcinationPhysical and Theoretical ChemistryBimetallic stripHydrodesulfurizationPalladiumJournal of Catalysis
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