0000000000052118
AUTHOR
Dmitry Yu. Naumov
Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores
Electron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.
Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons
The electron precise incomplete cuboidal complex [Mo(3)S(4)(dppe)(3)Br(3)]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo(3)S(4)(dppe)(3)(Br,Cl)(3)](Br,Cl) (1b) can be smoothly reduced to the paramagnetic [Mo(3)S(4)(dppe)(3)X(3)] clusters (2a, X = Br; 2b, X = Cl/Br) with 7 CSE by treatment with liquid Ga.
CCDC 1542006: Experimental Crystal Structure Determination
Related Article: Pavel A. Petrov, Dmitry Yu. Naumov, Taisiya S. Sukhikh, Sergey N. Konchenko, Carlos J. Gómez-García, Rosa Llusar|2017|New J.Chem.|41|7849|doi:10.1039/C7NJ01217A
CCDC 1542007: Experimental Crystal Structure Determination
Related Article: Pavel A. Petrov, Dmitry Yu. Naumov, Taisiya S. Sukhikh, Sergey N. Konchenko, Carlos J. Gómez-García, Rosa Llusar|2017|New J.Chem.|41|7849|doi:10.1039/C7NJ01217A