6533b7cefe1ef96bd1257a64

RESEARCH PRODUCT

Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

Carlos J. Gómez-garcíaSergey N. KonchenkoRosa LlusarDmitry Yu. NaumovPavel A. PetrovTaisiya S. Sukhikh

subject

010405 organic chemistryChemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCatalysisSpectral line0104 chemical scienceslaw.inventionDelocalized electronParamagnetismCrystallographyUnpaired electronlawComputational chemistryMolybdenumMaterials ChemistryCluster (physics)Ground stateElectron paramagnetic resonance

description

Electron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

yearjournalcountryeditionlanguage
2017-01-01
10.1039/c7nj01217a