0000000000056581

AUTHOR

Francisco J. Muñoz Lara

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Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers

2012

Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN)(4)]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.

Materials sciencePyrazineStereochemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsHysteresischemistry.chemical_compoundCrystallographychemistryThioureaSpin crossoverMaterials ChemistryCeramics and CompositesMoleculePlatinumThermal analysisPalladiumChemical Communications
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