6533b7cffe1ef96bd1257d48
RESEARCH PRODUCT
Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers
Ana B. GasparMasaaki OhbaFrancisco J. Muñoz LaraJosé Antonio RealM. Carmen MuñozRyo OhtaniSusumu KitagawaDaniel AravenaEliseo Ruizsubject
Materials sciencePyrazineStereochemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsHysteresischemistry.chemical_compoundCrystallographychemistryThioureaSpin crossoverMaterials ChemistryCeramics and CompositesMoleculePlatinumThermal analysisPalladiumdescription
Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN)(4)]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-04-06 | Chemical Communications |