Search results for "Pyrazine"

showing 10 items of 325 documents

CCDC 671674: Experimental Crystal Structure Determination

2011

Related Article: S.Shit, S.K.Dey, C.Rizzoli, E.Zangrando, G.Pilet, C.J.Gomez-Garcia, S.Mitra|2011|Inorg.Chim.Acta|370|18|doi:10.1016/j.ica.2011.01.008

(2-Hydroxy-N'-(555-trifluoro-4-(hydroxy)pent-3-en-2-ylidene)benzohydrazido)-(methanol)-(pyrazine)-copper(ii) perchlorateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 164934: Experimental Crystal Structure Determination

2001

Related Article: H.Grove, J.Sletten, M.Julve, F.Lloret|2001|J.Chem.Soc.,Dalton Trans.||2487|doi:10.1039/b103588f

(mu2-23-bis(2-Pyridyl)pyrazine-NN'N''N''')-aqua-tetrachloro-(dimethylsulfoxide-O)-di-copper(ii) dimethylsulfoxide solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 247407: Experimental Crystal Structure Determination

2005

Related Article: J.Carranza, J.Sletten, C.Brennan, F.Lloret, J.Cano, M.Julve|2004|Dalton Trans.||3997|doi:10.1039/b412034p

(mu2-Croconato)-(mu2-2356-tetrakis(2-pyridyl)pyrazine)-bis(croconato)-triaqua-tri-copper(ii) heptahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 685749: Experimental Crystal Structure Determination

2009

Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, J.L.Pizarro, M.I.Arriortua, L.Lezama, T.Rojo, M.Gonzalez-Alvarez, J.Borras, J.Garcia-Tojal|2008|J.Inorg.Biochem.|102|1910|doi:10.1016/j.jinorgbio.2008.06.015

(mu~2~-Pyrazine)-bis(pyridine-2-aldehyde thiosemicarbazone)-di-copper(ii) diperchlorateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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A Combined Experimental and Theoretical Study of the Ammonium Bifluoride Catalyzed Regioselective Synthesis of Quinoxalines and Pyrido[2,3-b]pyrazines

2015

International audience; Ammonium bifluoride was efficiently used (at a 0.5 mol % loading) to catalyze the cyclocondensation between 1,2-arylenediamines and 1,2-dicarbonyl compounds at room temperature in methanol-water, affording quinoxalines and pyrido[2,3-b]pyrazines in excellent yields. Importantly, 2,8-disubstituted quinoxalines and 3-substituted pyrido[2,3-b]pyrazines were regioselectively formed by reacting aryl glyoxals with 3-methyl-1,2-phenylenediamine and 2,3-diaminopyridine, respectively. Analysis of the DFT reactivity indices allowed to explain the catalytic role of ammonium bifluoride.

010405 organic chemistryChemistryOrganic ChemistryRegioselectivityAmmonium bifluoride010402 general chemistrypyrido[201 natural sciencesCatalysisammonium bifluoride0104 chemical sciencesCatalysischemistry.chemical_compoundregioselectivity3-b]pyrazinesDFT reactivity indices[CHIM]Chemical SciencesOrganic chemistryquinoxalinesDensity functional theoryReactivity (chemistry)Synthesis
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How to fight multiple enemies : target-specific chemical defences in an aposematic moth

2017

Animals have evolved different defensive strategies to survive predation, among which chemical defences are particularly widespread and diverse. Here we investigate the function of chemical defence diversity, hypothesizing that such diversity has evolved as a response to multiple enemies. The aposematic wood tiger moth (Arctia plantaginis) displays conspicuous hindwing coloration and secretes distinct defensive fluids from its thoracic glands and abdomen. We presented the two defensive fluids from laboratory-reared moths to two biologically relevant predators, birds and ants, and measured their reaction in controlled bioassays (no information on colour was provided). We found that defensive…

0106 biological sciences0301 basic medicineColorAposematismBiologyMoths010603 evolutionary biology01 natural sciencesGeneral Biochemistry Genetics and Molecular BiologyPredationBirds03 medical and health sciencesSpecies SpecificityAnimalsaposematismta116General Environmental ScienceGeneral Immunology and MicrobiologyEcologyEcologyAntsfungipredator–prey interactionschemical defencesGeneral MedicinepyrazinesBiological EvolutionBody Fluids030104 developmental biologyPredatory Behaviorta1181General Agricultural and Biological SciencesProceedings of the Royal Society B : Biological Sciences
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Crosstalk between angiotensin and the nonamyloidogenic pathway of Alzheimer's amyloid precursor protein.

2017

The association between hypertension and an increased risk for Alzheimer's disease (AD) and dementia is well established. Many data suggest that modulation of the renin-angiotensin system may be meaningful for the prevention and therapy of neurodegenerative disorders, in particular AD. Proteolytic cleavage of the amyloid precursor protein (APP) by α-secretase precludes formation of neurotoxic Aβ peptides and is expected to counteract the development of AD. An established approach for the up-regulation of α-secretase cleavage is the activation of G protein-coupled receptors (GPCRs). Therefore, our study aimed to analyze whether stimulation of angiotensin AT1 or AT2 receptors stably expressed…

0301 basic medicineAngiotensin receptorAngiotensinsBiochemistryReceptor Angiotensin Type 2Receptor Angiotensin Type 103 medical and health sciencesAmyloid beta-Protein PrecursorAlzheimer DiseaseCyclohexanesGTP-Binding Protein gamma SubunitsAmyloid precursor proteinHumansMolecular Biologybeta-ArrestinsG protein-coupled receptorAngiotensin II receptor type 1biologyChemistryGTP-Binding Protein beta SubunitsP3 peptideCell BiologyAmyloidosisAngiotensin IIGTP-Binding Protein alpha SubunitsBiochemistry of Alzheimer's diseaseCell biology030104 developmental biologyHEK293 CellsPyrazinesProteolysisbiology.proteinAmyloid Precursor Protein SecretasesAmyloid precursor protein secretaseThe FEBS journal
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Synthesis of Novel Polyazinyl-Substituted Triazolopyridines from [1,2,3]Triazolo[1,5-a]pyridines

2017

A series of 7-azinyl-substituted triazolopyridines and 3-(6-azi­nyl-substituted 2-pyridyl)triazolopyridines were synthesized by addition of the corresponding 3-substituted 7-lithiotriazolopyridine to pyrimidine, pyrazine, pyridazine, and 1,3,5-triazine respectively, followed by hydrolysis and oxidation.

0301 basic medicinePyrimidinePyrazine010405 organic chemistryOrganic Chemistry01 natural sciencesCatalysis0104 chemical sciencesPyridazine03 medical and health sciencesHydrolysischemistry.chemical_compound030104 developmental biologychemistryOrganic chemistrySynthesis
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CHK1-targeted therapy to deplete DNA replication-stressed, p53-deficient, hyperdiploid colorectal cancer stem cells.

2017

ObjectiveCancer stem cells (CSCs) are responsible for tumour formation and spreading, and their targeting is required for tumour eradication. There are limited therapeutic options for advanced colorectal cancer (CRC), particularly for tumours carrying RAS-activating mutations. The aim of this study was to identify novel CSC-targeting strategies.DesignTo discover potential therapeutics to be clinically investigated as single agent, we performed a screening with a panel of FDA-approved or investigational drugs on primary CRC cells enriched for CSCs (CRC-SCs) isolated from 27 patients. Candidate predictive biomarkers of efficacy were identified by integrating genomic, reverse-phase protein mic…

0301 basic medicinep53DNA ReplicationCELL CYCLE CONTROLDNA damageColorectal cancerColonmedicine.medical_treatmentAntineoplastic AgentsBiologyBioinformaticsmedicine.disease_causeDNA DAMAGETargeted therapy03 medical and health sciencesCancer stem cellCell Line TumormedicineHumansCHEK11506DRUG DEVELOPMENTOligonucleotide Array Sequence AnalysisMutationCOLORECTAL CANCERSettore MED/06 - ONCOLOGIA MEDICAGastroenterologyCHEMOTHERAPYmedicine.diseaseImmunohistochemistryPrexasertib030104 developmental biologyPyrazinesCheckpoint Kinase 1MutationCancer researchNeoplastic Stem CellsPyrazolesStem cellTumor Suppressor Protein p53Colorectal NeoplasmsGut
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CCDC 1575617: Experimental Crystal Structure Determination

2017

Related Article: Matthew M. Morgan, Evan A. Patrick, J. Mikko Rautiainen, Heikki M. Tuononen, Warren E. Piers, Denis M. Spasyuk|2017|Organometallics|36|2541|doi:10.1021/acs.organomet.7b00051

1267-tetrakis(4-t-butylphenyl)-510-dimethyl-38-diphenyl-38-diboratadipyrrolo[12-a:1'2'-d]pyrazine-49-diiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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