0000000000061001
AUTHOR
Sergei Lobanov
Study of the pyroelectricity in LiIns2 crystal
Abstract Pyroelectric current measurements performed on a LiInS2 monodomain single crystal show a linear variation of the current between 120 and 260 K. Near room temperature, a space charge relaxation screens pyroelectricity. The pyroelectric coefficient follows a linear thermal dependence leading to an extrapolated value of 6×10−10 C K−1 cm−2 at 300 K. As for other oxide-type pyroelectric compounds, this value is shown to be proportional to the electro-optic coefficient r333 of LiInS2.
Optical, thermal, electrical, damage, and phase-matching properties of lithium selenoindate
Lithium selenoindate (LiInSe2) is a new nonlinear chalcogenide biaxial crystal, related to LiInS2 and transparent from 0.54 to 10 μm at the 50% level (10 mm thickness), which has been successfully grown in large sizes and with good optical quality. We report on what we believe to be new physical properties that are relevant for laser and nonlinear optical applications and summarize all relevant characteristics, both from the literature and as measured in the present work. With respect to AgGaS(e)2 ternary chalcopyrite materials, LiInSe2 displays a nearly isotropic thermal expansion behavior with three- to five-times-larger thermal conductivities associated with high optical damage threshold…