Synthesis of β-P,N Aminophosphines and Coordination Chemistry to PdII. X-ray Structures of [PdCl2(Ph2PCH2CH(Ph)NHPh-κP,κN)] and [PdCl(η3-C3H5)(Ph2PCH2CH(Ph)NHPh-κP)]

The reaction of the CN bond in PhCHNPh with the carbanionic species Ph2PCH2-, leading to the N-phenyl β-aminophosphine Ph2PCH2CH(Ph)NHPh, L1, is described. This molecule reacts with different organ...