6533b7cffe1ef96bd125838b

RESEARCH PRODUCT

Synthesis of β-P,N Aminophosphines and Coordination Chemistry to PdII. X-ray Structures of [PdCl2(Ph2PCH2CH(Ph)NHPh-κP,κN)] and [PdCl(η3-C3H5)(Ph2PCH2CH(Ph)NHPh-κP)]

Jean-michel CamusJacques AndrieuJochen DietzPhilippe RichardRinaldo Poli

subject

chemistry.chemical_classification010405 organic chemistryChemistryStereochemistryX-ray010402 general chemistry01 natural sciencesMedicinal chemistry3. Good health0104 chemical sciencesCoordination complexInorganic ChemistryMoleculePhysical and Theoretical Chemistry

description

The reaction of the CN bond in PhCHNPh with the carbanionic species Ph2PCH2-, leading to the N-phenyl β-aminophosphine Ph2PCH2CH(Ph)NHPh, L1, is described. This molecule reacts with different organ...

https://doi.org/10.1021/ic000867y