0000000000065960
AUTHOR
I. P. Raevski
showing 6 related works from this author
Magnetic susceptibility of multiferroics and chemical ordering
2017
Magnetic susceptibility of two types of perovskite compounds A(Fe0.5M0.5)O3 A=Ba,Sr with M=Nb and Sb differing in the degree of chemical ordering was studied between 2 and 380 K. In the low temperature region, these compounds exhibit antiferromagnetic and spin-glass transition at T = 16−30 K. For the ordered compounds (M = Sb) the inverse susceptibility depends on T linearly up to the highest temperatures used. This enables the determination of the Weiss temperature θ and effective moment of the Fe3+ ion expressed by a number of Bohr magnetons, peff. In contrast to it, the compounds with M = Nb are characterized by a higher degree of the glassines and by a concave character of the inverse s…
Room-temperature paramagnetoelectric effect in magnetoelectric multiferroics Pb(Fe1/2Nb1/2)O3 and its solid solution with PbTiO3
2015
We have observed the magnetoelectric (ME) response at room temperature and above in high-resistive ceramics made of multiferroic Pb(Fe1/2Nb1/2)O3 (PFN) and PFN-based solid solution 0.91PFN-0.09PbTiO3 (PFN-PT). The value of the paramagnetoelectric (PME) coefficient shows a pronounced maximum near the ferroelectric-to-paraelectric phase transition temperature, T C, and then decreases sharply to zero for T > T C. The maximal PME coefficient in PFN is about 4 × 10−18 s/A. The theoretical description of the PME effect, within the framework of a Landau theory of phase transitions allowing for realistic temperature dependences of spontaneous polarization, dielectric and magnetic susceptibilities, …
Superspin glass phase and hierarchy of interactions in multiferroic PbFe1/2Sb1/2O3: an analog of ferroelectric relaxors?
2014
We have fabricated new perovskite multiferroic PbFeSbO3 with a high degree (up to 0.9) of chemical ordering and unexpectedly high-temperature magnetic relaxor properties, which can barely be described within concepts of conventional spin glass physics. Notably, we found that the field-temperature phase diagram of this material, in the extremely wide temperature interval, contains the de Almeida–Thouless-type critical line, which has been the subject of long debates regarding its possible experimental realization. We explain our findings by the creation, at high temperatures of not less than 250 K, of giant superspins (SSs), owing, curiously enough, to the antiferromagnetic superexchange int…
Magnetoelectric effect in antiferromagnetic multiferroic Pb(Fe1/2Nb1/2)O3 and its solid solutions with PbTiO3
2017
Antiferromagnets (AFMs) are presently considered as promising materials for applications in spintronics and random access memories due to the robustness of information stored in the AFM state against perturbing magnetic fields. In this respect, AFM multiferroics may be attractive alternatives for conventional AFMs as the coupling of magnetism with ferroelectricity (magnetoelectric effect) offers an elegant possibility of electric-field control and switching of AFM domains. Here we report the results of comprehensive experimental and theoretical investigations of the quadratic magnetoelectric (ME) effect in single crystals and highly resistive ceramics of $\mathrm{Pb}(\mathrm{F}{\mathrm{e}}_…
Chemical disorder and Pb207 hyperfine fields in the magnetoelectric multiferroic Pb(Fe1/2Sb1/2)O3 and its solid solution with Pb(Fe1/2Nb1/2)O3
2018
We report on the results of magnetic susceptibility, electron paramagnetic resonance, and $^{207}\mathrm{Pb}$ nuclear magnetic resonance (NMR) studies of the magnetoelectric multiferroic $\mathrm{Pb}(\mathrm{F}{\mathrm{e}}_{1/2}\mathrm{S}{\mathrm{b}}_{1/2}){\mathrm{O}}_{3}$ (PFS) ceramic, as well as its solid solution with $\mathrm{Pb}(\mathrm{F}{\mathrm{e}}_{1/2}\mathrm{N}{\mathrm{b}}_{1/2}){\mathrm{O}}_{3}$ (PFN) of different degrees of the 1:1 ordering of magnetic $\mathrm{F}{\mathrm{e}}^{3+}$ and nonmagnetic $\mathrm{S}{\mathrm{b}}^{5+}$ ions. The ordering has been studied by x-ray diffraction (XRD) and NMR methods. In particular, two spectral lines, originating from the ordered and dis…
Comparative studies of ferroelectric and magnetic phase transitions in Pb(Fe1/2Nb1/2)O3-PbMO3 (M-Ti, Zr) multiferroic solid solutions
2015
Some peculiar features of magnetic x,T-phase diagram of (1-x)PbFe1/2Nb1/2O3- xPbTiO3 system at x ≈ 0.1 have been ascribed previously to the change of the lattice symmetry from rhombohedral to tetragonal or to the decrease of the lattice parameter with x. We carried out structural, dielectric, magnetization, and Mossbauer studies of (1-x)PbFe1/2Nb1/2O3-xPbZrO3 system, where the symmetry remains rhombohedral, while the lattice parameter increases with x. However, the magnetic x,T-phase diagram of (1-x)PbFe1/2Nb1/2O3-xPbZrO3 appeared to be very similar to that of (1-x) PbFe1/2Nb1/2O3-xPbTiO3. Anomalies of composition dependence of magnetic phase transition temperatures at x ≈ 0.1 are supposed …