0000000000072827
AUTHOR
Antonella Glisenti
Surface Study of Pumice Supported Nickel Catalysts Used in the Hydrogenation of CO
A series of pumice supported nickel catalysts used in the CO hydrogenation reaction were characterised by X-ray photoelectron spectroscopy. Qualitative and quantitative analysis of the XPS peaks have shown the effect of the calcination conditions on the chemical state of the nickel before hydrogenation and the particle size of the metal after reduction. Calcination at high temperature determined enrichment of sodium ions on the surface of the support and also on the metal particles. After exposure to the gas mixture CO/H2, formation of nickel carbides and other carbon species was checked. The correlation found between the surface atomic ratio Na/Si and the activity and selectivity of the ca…
Plasma Functionalization of Multiwalled Carbon Nanotubes and Their Use in the Preparation of Nylon 6-Based Nanohybrids
The possibility to obtain carbon nanotubes (CNT)/polyamide 6 composites with excellent mechanical properties in a simple, industrially scalable way is investigated. Commercial CNTs are treated by plasma while changing some key parameters (exposure time, plasma power, type of gas) in order to optimize the process and to achieve a sufficient degree of functionalization. The treated samples are characterized by Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The most interesting samples are selected to be used as reinforcing fillers, in different concentrations, in a polyamide 6 matrix. The mechanical tests show a dramatic increase of both tens…
Plasma Functionalization of Multiwalled Carbon Nanotubes and Their Use in the Preparation of Nylon 6-Based Nanohybrids
The possibility to obtain carbon nanotubes (CNT)/polyamide 6 composites with excellent mechanical properties in a simple, industrially scalable way is investigated. Commercial CNTs are treated by plasma while changing some key parameters (exposure time, plasma power, type of gas) in order to optimize the process and to achieve a sufficient degree of functionalization. The treated samples are characterized by Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The most interesting samples are selected to be used as reinforcing fillers, in different concentrations, in a polyamide 6 matrix. The mechanical tests show a dramatic increase of both tens…