0000000000072981

AUTHOR

Sydney B. Sillart

showing 2 related works from this author

Aktive Anode auf Molybdänbasis für dehydrierende Kupplungen

2018

010405 organic chemistryChemistryGeneral Medicine010402 general chemistry01 natural sciences0104 chemical sciencesAngewandte Chemie
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Active Molybdenum‐Based Anode for Dehydrogenative Coupling Reactions

2018

A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher-valent molybdenum species. This system can replace powerful but stoichiometrically required MoV reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.

Materials science010405 organic chemistrychemistry.chemical_elementGeneral ChemistryElectrolyte010402 general chemistryElectrochemistry01 natural sciencesCombinatorial chemistryCatalysisCoupling reaction0104 chemical sciencesAnodechemistryMolybdenumReagentOxidative coupling of methaneStoichiometryAngewandte Chemie International Edition
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