6533b855fe1ef96bd12aff9e
RESEARCH PRODUCT
Active Molybdenum‐Based Anode for Dehydrogenative Coupling Reactions
Siegfried R. WaldvogelTimo MüllerPeter FranzmannAlexander BommWolfgang SchadeSydney B. SillartMichael HoltkampUwe KarstSebastian B. Beilsubject
Materials science010405 organic chemistrychemistry.chemical_elementGeneral ChemistryElectrolyte010402 general chemistryElectrochemistry01 natural sciencesCombinatorial chemistryCatalysisCoupling reaction0104 chemical sciencesAnodechemistryMolybdenumReagentOxidative coupling of methaneStoichiometrydescription
A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher-valent molybdenum species. This system can replace powerful but stoichiometrically required MoV reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-01-10 | Angewandte Chemie International Edition |