0000000000073531

AUTHOR

Benjamin Rousselle

showing 4 related works from this author

P-Chirogenic Triazole-Based Phosphine: Synthesis, Coordination Chemistry, and Asymmetric Catalysis

2020

chemistry.chemical_classification010405 organic chemistryOrganic ChemistryEnantioselective synthesisTriazole010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical sciencesCoordination complexchemistry.chemical_compoundchemistryTransition metalPhysical and Theoretical ChemistryPhosphineEuropean Journal of Organic Chemistry
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Synthesis of ortho-fonctionnalized arylphosphines and their applications

2020

This thesis reports with the synthesis of ortho-functionnalized phosphines bearing phosphonium and 1,2,3-triazole moieties.The synthesis of phosphines-phosphoniums, using as key-step Phospha-Fries rearrangement and Appel reaction is described. Eight new phosphines- phosphoniums, bearing aryl, alkyl or ferrocenyl fragments on the phosphonium part, have been prepared with overall yields reaching 48%. These phosphines- phosphoniums have been used in the preparation of gold (I) complexes which have been characterized using spectroscopic methods and X ray diffraction. Both gold (I) complexes and phosphines-phosphoniums have been studied in biology and these compounds turned out to be cytotoxic i…

Phosphines ortho-FonctionnaliséesPhosphines-Triazoles P-ChirogéniquesCatalyse asymétriqueP-Chirogenic phosphines-TriazolesAsymmetric catalysis[CHIM.CRIS]Chemical Sciences/CristallographyOrtho-Fonctionnalized phosphinesPhosphines-PhosphoniumsComplexes d’or (I)[CHIM.CRIS] Chemical Sciences/CristallographyGold (I) complexesChimie de coordinationCoordination chemistry
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CCDC 1953273: Experimental Crystal Structure Determination

2020

Related Article: Jérôme Bayardon, Benjamin Rousselle, Yoann Rousselin, Quentin Bonnin, Raluca Malacea-Kabbara|2020|Eur.J.Org.Chem.|2020|4723|doi:10.1002/ejoc.202000723

Space GroupCrystallographyCrystal SystemCrystal Structure(4-{2-[(2-methoxyphenyl)(phenyl)phosphanyl]phenyl}-1-phenyl-1H-123-triazole)-allyl-palladium hexafluorophosphate dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1953272: Experimental Crystal Structure Determination

2020

Related Article: Jérôme Bayardon, Benjamin Rousselle, Yoann Rousselin, Quentin Bonnin, Raluca Malacea-Kabbara|2020|Eur.J.Org.Chem.|2020|4723|doi:10.1002/ejoc.202000723

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{2-[(2-methoxyphenyl)(phenyl)phosphanyl]phenyl}-1-phenyl-1H-123-triazoleExperimental 3D Coordinates
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